Phase Behavior of (1-Alkyl-3-methyl Imidazolium Tetrafluoroborate+6-(Hydroxymethyl)oxane-2,3,4,5-tetrol + Water)

CORC > 过程工程研究所 > 中国科学院过程工程研究所 > 湿法冶金清洁生产技术国家工程实验室

	Phase Behavior of (1-Alkyl-3-methyl Imidazolium Tetrafluoroborate+6-(Hydroxymethyl)oxane-2,3,4,5-tetrol + Water)
	Chen, Yuhuan 2; Zhang, Suojiang 1
刊名	JOURNAL OF CHEMICAL AND ENGINEERING DATA
	2010
卷号	55 期号:1 页码:278-282
关键词	AQUEOUS BIPHASIC SYSTEMS LIQUID-LIQUID EQUILIBRIA IONIC LIQUIDS 2-PHASE SYSTEMS PLUS SUCROSE 298.15 K WATER TEMPERATURE EXTRACTION SALTS
ISSN号	0021-9568
通讯作者	Zhang, SJ
英文摘要	Phase behavior of 1-alkyl-3-methyl imidazolium tetrafluoroborate ([C(n)mim][BF(4)], n = 2 to 10), 6-(hydroxymethyl)oxane-2,3,4,5-tetrol and water has been determined at temperatures in the range of (242.15 to 308.15) K. Binodal Curves, tie-lines, and the slope of the tie-line (STL) for [C(3)min][BF(4)]/[C(4)mim][BF(4)] + glucose + H(2)O systems were obtained at different temperatures of T = (278.15, 288.15, 298.15, and 308.15) K. Results show that, as the temperature decreases, the two-phase area expands and the STIL increases. Binodal curves were correlated using ail empirical equation, and tie-lines were correlated according to the Othmer-Tobias and Bancroft equations. These equations satisfactorily represented the experimental data. The molecular structure is used as ail argument to describe the phase-forming mechanism.
WOS标题词	Science & Technology ; Physical Sciences ; Technology
类目[WOS]	Chemistry, Multidisciplinary ; Engineering, Chemical
研究领域[WOS]	Chemistry ; Engineering
关键词[WOS]	AQUEOUS BIPHASIC SYSTEMS ; LIQUID-LIQUID EQUILIBRIA ; IONIC LIQUIDS ; 2-PHASE SYSTEMS ; PLUS SUCROSE ; 298.15 K ; WATER ; TEMPERATURE ; EXTRACTION ; SALTS
收录类别	SCI
语种	英语
WOS记录号	WOS:000273405200041
公开日期	2013-11-28
内容类型	期刊论文
版本	出版稿
源URL	[http://ir.ipe.ac.cn/handle/122111/6245]
专题	过程工程研究所_湿法冶金清洁生产技术国家工程实验室
作者单位	1.Chinese Acad Sci, Res Lab Green Chem & Technol, Inst Proc Engn, Beijing 100080, Peoples R China 2.Hebei Univ Technol, Sch Chem Engn & Technol, Tianjin 300130, Peoples R China
推荐引用方式 GB/T 7714	Chen, Yuhuan,Zhang, Suojiang. Phase Behavior of (1-Alkyl-3-methyl Imidazolium Tetrafluoroborate+6-(Hydroxymethyl)oxane-2,3,4,5-tetrol + Water)[J]. JOURNAL OF CHEMICAL AND ENGINEERING DATA,2010,55(1):278-282.
APA	Chen, Yuhuan,&Zhang, Suojiang.(2010).Phase Behavior of (1-Alkyl-3-methyl Imidazolium Tetrafluoroborate+6-(Hydroxymethyl)oxane-2,3,4,5-tetrol + Water).JOURNAL OF CHEMICAL AND ENGINEERING DATA,55(1),278-282.
MLA	Chen, Yuhuan,et al."Phase Behavior of (1-Alkyl-3-methyl Imidazolium Tetrafluoroborate+6-(Hydroxymethyl)oxane-2,3,4,5-tetrol + Water)".JOURNAL OF CHEMICAL AND ENGINEERING DATA 55.1(2010):278-282.