Bio-Inspired Polydopamine: A Versatile and Powerful Platform for Covalent Synthesis of Molecular Sieve Membranes | |
Huang AS(黄爱生) ; Qian Liu,† Nanyi Wang,‡ Jürgen Caro,‡ and Aisheng Huang*,† | |
刊名 | Journal of the American Chemical Society
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2013-11-13 | |
期号 | 47页码:17679—17682 |
通讯作者 | 黄爱生 |
合作状况 | 李雨桐 |
中文摘要 | Inspired by the bioadhesive ability of the marine mussel, a simple, versatile, and powerful synthesis strategy was developed to prepare highly reproducible and permselective molecular sieve membranes by using polydopamine as a novel covalent linker. Attributing to the formation of strong covalent and noncovalent bonds, ZIF-8 nutrients are attracted and bound to the support surface, thus promoting the ZIF-8 nucleation and the growth of uniform, well intergrown, and phase-pure ZIF-8 molecular sieve membranes. The developed ZIF-8 membranes show high hydrogen selectivity and thermal stability. At 150 °C and 1 bar, the mixture separation factors of H2/CO2, H2/N2, H2/CH4, and H2/C3H8 are 8.9, 16.2, 31.5 and 712.6, with H2 permeances higher than 1.8 × 10?7 mol·m?2·s?1·Pa?1, which is promising for hydrogen separation and purification. |
学科主题 | 物理化学 |
原文出处 | SCI收录 |
公开日期 | 2013-12-16 |
内容类型 | 期刊论文 |
源URL | [http://ir.nimte.ac.cn/handle/174433/10090] ![]() |
专题 | 宁波材料技术与工程研究所_宁波所知识产出 |
推荐引用方式 GB/T 7714 | Huang AS,Qian Liu,† Nanyi Wang,‡ Jürgen Caro,‡ and Aisheng Huang*,†. Bio-Inspired Polydopamine: A Versatile and Powerful Platform for Covalent Synthesis of Molecular Sieve Membranes[J]. Journal of the American Chemical Society,2013(47):17679—17682. |
APA | Huang AS,&Qian Liu,† Nanyi Wang,‡ Jürgen Caro,‡ and Aisheng Huang*,†.(2013).Bio-Inspired Polydopamine: A Versatile and Powerful Platform for Covalent Synthesis of Molecular Sieve Membranes.Journal of the American Chemical Society(47),17679—17682. |
MLA | Huang AS,et al."Bio-Inspired Polydopamine: A Versatile and Powerful Platform for Covalent Synthesis of Molecular Sieve Membranes".Journal of the American Chemical Society .47(2013):17679—17682. |
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