Size Effect of Gold Nanoparticles in Catalytic Reduction of p-Nitrophenol with NaBH4
周生虎,Zhen Ma,Dayin Hua ; Chao Lin 1,2, Kai Tao 1, Dayin Hua 2,*, Zhen Ma 3,* and Shenghu Zhou 1,*
刊名Molecules
2013-10-11
卷号37期号:10页码:12609—12620
通讯作者周生虎,Zhen Ma,Dayin Hua
合作状况李雨桐
中文摘要Gold nanoparticles (Au NPs) were prepared by reducing HAuCl4 with NaBH4. Their average particle sizes could be tuned in the range of 1.7 and 8.2 nm, by adjusting the amount of NaBH4 used during synthesis. The obtained Au NPs (colloids) were then loaded onto a commercial Al2O3 support to prepare Au/Al2O3 catalysts with tunable Au particle sizes. An optimal pH value (5.9) of the Au colloid solution was found to be essential for loading Au NPs onto Al2O3 while avoiding the growth of Au NPs. Au NPs and Au/Al2O3 catalysts were tested in the reduction of p-nitrophenol with NaBH4. Interestingly, the catalytic activity depended on the size of Au NPs, being the highest when the average size was 3.4 nm. Relevant characterization by UV-Vis, TEM, and XRD was conducted.
学科主题催化化学
原文出处SCI收录
公开日期2013-12-16
内容类型期刊论文
源URL[http://ir.nimte.ac.cn/handle/174433/10057]  
专题宁波材料技术与工程研究所_宁波所知识产出
推荐引用方式
GB/T 7714
周生虎,Zhen Ma,Dayin Hua,Chao Lin 1,2, Kai Tao 1, Dayin Hua 2,*, Zhen Ma 3,* and Shenghu Zhou 1,*. Size Effect of Gold Nanoparticles in Catalytic Reduction of p-Nitrophenol with NaBH4[J]. Molecules,2013,37(10):12609—12620.
APA 周生虎,Zhen Ma,Dayin Hua,&Chao Lin 1,2, Kai Tao 1, Dayin Hua 2,*, Zhen Ma 3,* and Shenghu Zhou 1,*.(2013).Size Effect of Gold Nanoparticles in Catalytic Reduction of p-Nitrophenol with NaBH4.Molecules,37(10),12609—12620.
MLA 周生虎,Zhen Ma,Dayin Hua,et al."Size Effect of Gold Nanoparticles in Catalytic Reduction of p-Nitrophenol with NaBH4".Molecules 37.10(2013):12609—12620.
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