Facile Synthesis of Aluminum-Based Metal-Organic Frameworks with Different Morphologies and Structure through an OH--Assisted Method

CORC > 宁波材料技术与工程研究所 > 中国科学院宁波材料技术与工程研究所 > 宁波所知识产出

	Facile Synthesis of Aluminum-Based Metal-Organic Frameworks with Different Morphologies and Structure through an OH--Assisted Method
	陈亮，孔春龙 ; Yichao Lin, Chunlong Kong,* and Liang Chen*[a]
刊名	Chem. Asian J.
	2013-05-24
卷号	42 期号:8 页码:1873—1878
通讯作者	陈亮，孔春龙
合作状况	李雨桐
中文摘要	We report the facile synthesis of aluminum-based metal–organic frameworks (MOFs) with different morphologies and structures by tuning the OH content in the reaction solution. MIL-96 crystals with dodecahedral and hexagonal column shapes were successfully synthesized by tuning the OH ion content of the synthesis solution. When the OH ion content was further increased, MIL-110 with a nanorod morphology appeared as the product. For the first time, we obtained pure MIL-96 and MIL-110 under basic conditions directly by using the 1,3,5- benzenetricarboxylic acid (btc) linker. All samples show significant thermal stability, with a decomposition temperature above 300 8C. We found that the gas adsorption properties of MIL-96 were directly dominated by the crystal morphology. At 0.4 8C and 30 bar, the dodecahedral and hexagonal MIL-96 samples can adsorb 9.3 and 6.5 mmolg 1 CO2, respectively, although they possess similar surface areas and identical crystalline structures. The MIL-110 nanorod shows a CO2 adsorption capacity of up to 16 mmolg 1 under the same conditions.
学科主题	物理化学
原文出处	其他国内刊物
公开日期	2013-12-16
内容类型	期刊论文
源URL	[http://ir.nimte.ac.cn/handle/174433/9921]
专题	宁波材料技术与工程研究所_宁波所知识产出
推荐引用方式 GB/T 7714	陈亮，孔春龙,Yichao Lin, Chunlong Kong,* and Liang Chen*[a]. Facile Synthesis of Aluminum-Based Metal-Organic Frameworks with Different Morphologies and Structure through an OH--Assisted Method[J]. Chem. Asian J.,2013,42(8):1873—1878.
APA	陈亮，孔春龙,&Yichao Lin, Chunlong Kong,* and Liang Chen*[a].(2013).Facile Synthesis of Aluminum-Based Metal-Organic Frameworks with Different Morphologies and Structure through an OH--Assisted Method.Chem. Asian J.,42(8),1873—1878.
MLA	陈亮，孔春龙,et al."Facile Synthesis of Aluminum-Based Metal-Organic Frameworks with Different Morphologies and Structure through an OH--Assisted Method".Chem. Asian J. 42.8(2013):1873—1878.