Facile Synthesis of Aluminum-Based Metal-Organic Frameworks with Different Morphologies and Structure through an OH--Assisted Method | |
陈亮,孔春龙 ; Yichao Lin, Chunlong Kong,* and Liang Chen*[a] | |
刊名 | Chem. Asian J.
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2013-05-24 | |
卷号 | 42期号:8页码:1873—1878 |
通讯作者 | 陈亮,孔春龙 |
合作状况 | 李雨桐 |
中文摘要 | We report the facile synthesis of aluminum-based metal–organic frameworks (MOFs) with different morphologies and structures by tuning the OH content in the reaction solution. MIL-96 crystals with dodecahedral and hexagonal column shapes were successfully synthesized by tuning the OH ion content of the synthesis solution. When the OH ion content was further increased, MIL-110 with a nanorod morphology appeared as the product. For the first time, we obtained pure MIL-96 and MIL-110 under basic conditions directly by using the 1,3,5- benzenetricarboxylic acid (btc) linker. All samples show significant thermal stability, with a decomposition temperature above 300 8C. We found that the gas adsorption properties of MIL-96 were directly dominated by the crystal morphology. At 0.4 8C and 30 bar, the dodecahedral and hexagonal MIL-96 samples can adsorb 9.3 and 6.5 mmolg 1 CO2, respectively, although they possess similar surface areas and identical crystalline structures. The MIL-110 nanorod shows a CO2 adsorption capacity of up to 16 mmolg 1 under the same conditions. |
学科主题 | 物理化学 |
原文出处 | 其他国内刊物 |
公开日期 | 2013-12-16 |
内容类型 | 期刊论文 |
源URL | [http://ir.nimte.ac.cn/handle/174433/9921] ![]() |
专题 | 宁波材料技术与工程研究所_宁波所知识产出 |
推荐引用方式 GB/T 7714 | 陈亮,孔春龙,Yichao Lin, Chunlong Kong,* and Liang Chen*[a]. Facile Synthesis of Aluminum-Based Metal-Organic Frameworks with Different Morphologies and Structure through an OH--Assisted Method[J]. Chem. Asian J.,2013,42(8):1873—1878. |
APA | 陈亮,孔春龙,&Yichao Lin, Chunlong Kong,* and Liang Chen*[a].(2013).Facile Synthesis of Aluminum-Based Metal-Organic Frameworks with Different Morphologies and Structure through an OH--Assisted Method.Chem. Asian J.,42(8),1873—1878. |
MLA | 陈亮,孔春龙,et al."Facile Synthesis of Aluminum-Based Metal-Organic Frameworks with Different Morphologies and Structure through an OH--Assisted Method".Chem. Asian J. 42.8(2013):1873—1878. |
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