pattern-based recognition for determination of enantiomeric excess, using chiral auxiliary induced chemical shift perturbation nmr
Lei Xinxiang ; Liu Lu ; Chen Xiaojing ; Yu Xiaochun ; Ding Lisheng ; Zhang Anjiang
刊名ORGANIC LETTERS
2010
卷号12期号:11页码:2540-2543
ISSN号1523-7060
学科主题Chemistry, Organic
收录类别SCI
语种英语
公开日期2011-05-10
附注A protocol for the determination of enantiomeric excess of chiral carboxylic acid, using the subtle frequency shifts (chemical shift perturbation) in NMR spectra induced by chiral auxiliary, is described. The spectra were analyzed with two pattern recognition protocols. Principal component analysis demonstrated good enantioselective separation of the analytes, and partial least-squares was used to analyze ee values of unknown samples.
内容类型期刊论文
源URL[http://ir.nimte.ac.cn/handle/174433/1608]  
专题宁波材料技术与工程研究所_宁波所知识产出
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GB/T 7714
Lei Xinxiang,Liu Lu,Chen Xiaojing,et al. pattern-based recognition for determination of enantiomeric excess, using chiral auxiliary induced chemical shift perturbation nmr[J]. ORGANIC LETTERS,2010,12(11):2540-2543.
APA Lei Xinxiang,Liu Lu,Chen Xiaojing,Yu Xiaochun,Ding Lisheng,&Zhang Anjiang.(2010).pattern-based recognition for determination of enantiomeric excess, using chiral auxiliary induced chemical shift perturbation nmr.ORGANIC LETTERS,12(11),2540-2543.
MLA Lei Xinxiang,et al."pattern-based recognition for determination of enantiomeric excess, using chiral auxiliary induced chemical shift perturbation nmr".ORGANIC LETTERS 12.11(2010):2540-2543.
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