pattern-based recognition for determination of enantiomeric excess, using chiral auxiliary induced chemical shift perturbation nmr | |
Lei Xinxiang ; Liu Lu ; Chen Xiaojing ; Yu Xiaochun ; Ding Lisheng ; Zhang Anjiang | |
刊名 | ORGANIC LETTERS
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2010 | |
卷号 | 12期号:11页码:2540-2543 |
ISSN号 | 1523-7060 |
学科主题 | Chemistry, Organic |
收录类别 | SCI |
语种 | 英语 |
公开日期 | 2011-05-10 |
附注 | A protocol for the determination of enantiomeric excess of chiral carboxylic acid, using the subtle frequency shifts (chemical shift perturbation) in NMR spectra induced by chiral auxiliary, is described. The spectra were analyzed with two pattern recognition protocols. Principal component analysis demonstrated good enantioselective separation of the analytes, and partial least-squares was used to analyze ee values of unknown samples. |
内容类型 | 期刊论文 |
源URL | [http://ir.nimte.ac.cn/handle/174433/1608] ![]() |
专题 | 宁波材料技术与工程研究所_宁波所知识产出 |
推荐引用方式 GB/T 7714 | Lei Xinxiang,Liu Lu,Chen Xiaojing,et al. pattern-based recognition for determination of enantiomeric excess, using chiral auxiliary induced chemical shift perturbation nmr[J]. ORGANIC LETTERS,2010,12(11):2540-2543. |
APA | Lei Xinxiang,Liu Lu,Chen Xiaojing,Yu Xiaochun,Ding Lisheng,&Zhang Anjiang.(2010).pattern-based recognition for determination of enantiomeric excess, using chiral auxiliary induced chemical shift perturbation nmr.ORGANIC LETTERS,12(11),2540-2543. |
MLA | Lei Xinxiang,et al."pattern-based recognition for determination of enantiomeric excess, using chiral auxiliary induced chemical shift perturbation nmr".ORGANIC LETTERS 12.11(2010):2540-2543. |
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