One-Pot Synthesis of Pd Nanoparticle Catalysts Supported on N-Doped Carbon and Application in the Domino Carbonylation | |
Li ZL(李泽龙)1,2; Liu JH(刘建华)1; Huang ZW(黄志威)1; Yang Y(杨英)1; Xia CG(夏春谷)1; Li FW(李福伟)1; Xia CG(夏春谷); Li FW(李福伟) | |
刊名 | ACS Catalysis |
2013 | |
卷号 | 3期号:5页码:839-845 |
关键词 | N-doped carbon N-heterocyclic carbenes supported catalysts nanoparticles carbonylation |
ISSN号 | 2155-5435 |
通讯作者 | 夏春谷 ; 李福伟 |
英文摘要 | In this work, we report a novel and facile procedure for a one-pot preparation of palladium nanoparticle catalysts supported on porous N-doped carbon (Pd@CNT) by direct carbonization of palladium-N-heterocyclic carbene coordination polymer (P-Pd-NHC). This method could be conveniently extended to the synthesis of the Ni and alloy (PdxNiy) nanoparticle catalysts (Ni@CN800, PdxNiy@CN800). The treatment temperature played an important role on the growth and properties of the resultant M@CNT, wherein M@CN800 carbonized at 800 ℃ showed well-monodispersed metal nanoparticles (MNPs), graphene-like layers of the N-doped carbon supports, and strong interaction between MNPs and the support. Pd@CN800 displayed high efficiency and stable recyclability toward the domino carbonylative synthesis of pyrazole derivatives. Interestingly, its catalytic performance has been even higher than that of the representative PdCl2(PPh3)2 within six runs. |
学科主题 | 物理化学与绿色催化 |
收录类别 | SCI |
资助信息 | the Chinese Academy of Sciences;the National Natural Science Foundation of China (21002106;21133011) |
语种 | 英语 |
WOS记录号 | WOS:000318589100006 |
公开日期 | 2013-12-19 |
内容类型 | 期刊论文 |
源URL | [http://210.77.64.217/handle/362003/4795] |
专题 | 兰州化学物理研究所_OSSO国家重点实验室 |
通讯作者 | Xia CG(夏春谷); Li FW(李福伟) |
作者单位 | 1.Chinese Acad Sci, Lanzhou Inst Chem Phys, State Key Lab Oxo Synth & Select Oxidat, Lanzhou 730000, Gansu, Peoples R China 2.Univ Chinese Acad Sci, Beijing 100049, Peoples R China |
推荐引用方式 GB/T 7714 | Li ZL,Liu JH,Huang ZW,et al. One-Pot Synthesis of Pd Nanoparticle Catalysts Supported on N-Doped Carbon and Application in the Domino Carbonylation[J]. ACS Catalysis,2013,3(5):839-845. |
APA | Li ZL.,Liu JH.,Huang ZW.,Yang Y.,Xia CG.,...&李福伟.(2013).One-Pot Synthesis of Pd Nanoparticle Catalysts Supported on N-Doped Carbon and Application in the Domino Carbonylation.ACS Catalysis,3(5),839-845. |
MLA | Li ZL,et al."One-Pot Synthesis of Pd Nanoparticle Catalysts Supported on N-Doped Carbon and Application in the Domino Carbonylation".ACS Catalysis 3.5(2013):839-845. |
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