Bioinspired Manganese and Iron Complexes with Tetradentate N Ligands for the Asymmetric Epoxidation of Olefins

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	Bioinspired Manganese and Iron Complexes with Tetradentate N Ligands for the Asymmetric Epoxidation of Olefins
	Wang XE(王晓娥)1,2; Miao CX(苗成霞)1 ; Wang SF(王寿峰)1 ; Xia CG(夏春谷)1 ; Sun W(孙伟)1
刊名	ChemCatChem
	2013
卷号	5 期号:8 页码:2489-2494
关键词	asymmetric epoxidation iron manganese N(4)ligand olefin
ISSN号	1867-3880
通讯作者	孙伟
英文摘要	The manganese and iron complexes with the tetradentate N ligand (1R,2R)-N,N'-dimethyl-N,N'-bis(1-methyl-2-benzimidazolylmethyl)cyclohexane-1,2-diamine have been synthesized and characterized. cis- configuration. Both the manganese and iron complexes are active catalysts for the asymmetric epoxidation of olefins with H₂O₂ as an oxidant and acetic acid as an additive. Up to 96% ee was observed for the epoxidation of α,β-unsaturated ketones at -20 ℃.
学科主题	物理化学与绿色催化
收录类别	SCI
资助信息	the Chinese Academy of Sciences;the National Natural Science Foundation of China (21133011;21073210)
语种	英语
WOS记录号	WOS:000322240600057
公开日期	2013-12-18
内容类型	期刊论文
源URL	[http://210.77.64.217/handle/362003/4765]
专题	兰州化学物理研究所_OSSO国家重点实验室
作者单位	1.Chinese Acad Sci, Lanzhou Inst Chem Phys, State Key Lab Oxo Synth & Select Oxidat, Lanzhou 730000, Peoples R China 2.Chinese Acad Sci, Grad Sch, Beijing 100039, Peoples R China
推荐引用方式 GB/T 7714	Wang XE,Miao CX,Wang SF,et al. Bioinspired Manganese and Iron Complexes with Tetradentate N Ligands for the Asymmetric Epoxidation of Olefins[J]. ChemCatChem,2013,5(8):2489-2494.
APA	Wang XE,Miao CX,Wang SF,Xia CG,&Sun W.(2013).Bioinspired Manganese and Iron Complexes with Tetradentate N Ligands for the Asymmetric Epoxidation of Olefins.ChemCatChem,5(8),2489-2494.
MLA	Wang XE,et al."Bioinspired Manganese and Iron Complexes with Tetradentate N Ligands for the Asymmetric Epoxidation of Olefins".ChemCatChem 5.8(2013):2489-2494.