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	Syntheses and Structures of Mononuclear, Dinuclear and Polynuclear Silver(I) Complexes of 2‑Pyrazole-Substituted 1,10-Phenanthroline Ligands
	Yang PJ(杨培菊)1; Cui FJ(崔凤娟)1; Yang XJ(杨晓娟)1; Wu B(吴彪)2,3
刊名	Crystal Growth and Design
	2013
卷号	13期号:1页码:186-194
ISSN号	1528-7483
通讯作者	吴彪
英文摘要	A series of mononuclear, dinuclear and polynuclear silver(I) complexes (1−6) bearing 2-pyrazolesubstituted 1,10-phenanthroline derivatives (L1, FL1, L2) have been synthesized and characterized by 1H and 13C NMR, IR spectroscopy, elemental analysis, and single crystal X-ray diffraction. Reaction of L1 (L1 = 2-(3,5-dimethylpyrazol-1-yl)- 1,10-phenanthroline) with AgClO4 or AgBF4 afforded two dinuclear silver(I) complexes [Ag2(L1)2(CH3CN)2](ClO4)2 (1) and [Ag2(L1)2(CH3CN)2](BF4)2 (2), in which two [AgL1(CH3CN)]+ units are linked by Ag···Ag interaction (Ag···Ag separation: 3.208(2) and 3.248(1) Å, respectively). A one-dimensional polymer {[AgL1](BF4)}∞ (3) consisting of an infinite ···Ag···Ag···Ag··· chain (Ag···Ag separation: 3.059(1) Å), as well as a dinuclear complex [Ag2(ClO4)2(L1)2] (4) in which the perchlorate anions instead of solvents are involved in the metal coordination, have also been obtained. The mononuclear complex [Ag(FL1)2](BF4) (5) was synthesized from FL1 (FL1 = 2-(3,5-bis(trifluoromethyl)pyrazol-1-yl)-1,10-phenanthroline) and AgBF4, while the dinuclear [Ag2(BF4)2(L2)2] (6) was isolated from L2 (L2 = 2-[N-(3-methyl-5-phenylpyrazole)]-1,10-phenanthroline). The photoluminescence properties of the ligands and complexes 1−6 have been studied both in the solid state and in solution.
学科主题	物理化学与绿色催化
收录类别	SCI
语种	英语
WOS记录号	WOS:000313143900024
公开日期	2013-12-16
内容类型	期刊论文
源URL	[http://210.77.64.217/handle/362003/4717]
专题	兰州化学物理研究所_OSSO国家重点实验室 兰州化学物理研究所_ERC国家工程研究中心
作者单位	1.Chinese Acad Sci, Lanzhou Inst Chem Phys, State Key Lab Oxo Synth & Select Oxidat, Lanzhou 730000, Peoples R China 2.NW Univ Xian, Coll Chem & Mat Sci, Xian 710069, Peoples R China 3.Lanzhou Univ, Coll Chem & Chem Engn, State Key Lab Appl Organ Chem, Lanzhou 730000, Peoples R China
推荐引用方式 GB/T 7714	Yang PJ,Cui FJ,Yang XJ,et al. Syntheses and Structures of Mononuclear, Dinuclear and Polynuclear Silver(I) Complexes of 2‑Pyrazole-Substituted 1,10-Phenanthroline Ligands[J]. Crystal Growth and Design,2013,13(1):186-194.
APA	Yang PJ,Cui FJ,Yang XJ,&Wu B.(2013).Syntheses and Structures of Mononuclear, Dinuclear and Polynuclear Silver(I) Complexes of 2‑Pyrazole-Substituted 1,10-Phenanthroline Ligands.Crystal Growth and Design,13(1),186-194.
MLA	Yang PJ,et al."Syntheses and Structures of Mononuclear, Dinuclear and Polynuclear Silver(I) Complexes of 2‑Pyrazole-Substituted 1,10-Phenanthroline Ligands".Crystal Growth and Design 13.1(2013):186-194.

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