Self-healing electrochromic energy storage devices based on PEDOT:PSS | |
Y. Meng, J. Li, X. Yang, Y. Gao, X. Li, L. Wang and W. Lu | |
刊名 | Journal of Materials Chemistry C
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2023 | |
卷号 | 11期号:40页码:13752-13762 |
ISSN号 | 20507526 |
DOI | 10.1039/d3tc02458j |
英文摘要 | Poly (3,4-ethylenedioxythiophene): poly (4-styrenesulfonic acid) (PEDOT:PSS) is a kind of widely used polymer with excellent electrical conductivity. In this study, PEDOT:PSS was modified to achieve self-healing ability while maintaining excellent energy storage properties. The modified PEDOT:PSS hybrid film demonstrated instantaneous self-healing ability due to physical cross-linking after being subjected to different external cuts (the average self-healing time was 1.44 s). When pressed at different rates, the film had a self-healing time of less than 0.12 s, and a retention rate of 74% after pressing 1750 times consecutively at a rate of 8.6 cm s−1. The mechanism of self-healing was investigated using theoretical calculations. Tungsten trioxide (WO3) was further introduced into the PEDOT:PSS hybrid film to fabricate electrochromic energy storage devices (EESDs), achieving a specific capacitance of 105.35 mF cm−2 and a capacitance retention of 98.2% after 1000 cycles. In the organic/inorganic hybrid system, the modified PEDOT:PSS film acted as both a protective coating for WO3 and exhibited a synergistic color change with WO3, ultimately improving the overall performance of the device. The present self-healing strategy can help design restorers for EESDs and can be extended to other new rechargeable electrochromic battery systems with good application prospects. © 2023 The Royal Society of Chemistry |
URL标识 | 查看原文 |
内容类型 | 期刊论文 |
源URL | [http://ir.ciomp.ac.cn/handle/181722/67769] ![]() |
专题 | 中国科学院长春光学精密机械与物理研究所 |
推荐引用方式 GB/T 7714 | Y. Meng, J. Li, X. Yang, Y. Gao, X. Li, L. Wang and W. Lu. Self-healing electrochromic energy storage devices based on PEDOT:PSS[J]. Journal of Materials Chemistry C,2023,11(40):13752-13762. |
APA | Y. Meng, J. Li, X. Yang, Y. Gao, X. Li, L. Wang and W. Lu.(2023).Self-healing electrochromic energy storage devices based on PEDOT:PSS.Journal of Materials Chemistry C,11(40),13752-13762. |
MLA | Y. Meng, J. Li, X. Yang, Y. Gao, X. Li, L. Wang and W. Lu."Self-healing electrochromic energy storage devices based on PEDOT:PSS".Journal of Materials Chemistry C 11.40(2023):13752-13762. |
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