The effect of COH fluids on partial melting of eclogite and lherzolite under moderately oxidizing and reducing conditions
Zairong Liu1,2,3; Arno Rohrbach1; Carla Tiraboschi1; Stephen F. Foley3; Jasper Berndt1; Stephan Klemme1
刊名Chemical Geology
2023-01-20
卷号616期号:2023页码:121219
关键词COH fluids Reduced mantle Lherzolite Partial melting Komatiite Eclogite
DOI10.1016/j.chemgeo.2022.121219
通讯作者Zairong Liu
英文摘要

Fluids rich in water and carbon (COH) are among the most reactive agents of mantle metasomatism and play a major role in the continuous degassing of the Earth. The addition of small amounts of H2O and CO2 depress the solidus of mantle peridotite by several hundred degrees, resulting in the common occurrence of highly mobile, volatile-rich melts, which are a main cause of heterogeneities in the Earth's mantle. Most experimental studies have investigated relatively oxidizing conditions in which COH fluids are mixtures of H2O + CO2, whereas ex-periments on the partial melting of mafic and ultramafic rocks under reducing conditions, in which CH4 + H2O mixtures occur, remain sparse. We have performed experiments on eclogite and lherzolite compositions at pressures from 1.8 to 6 GPa, and temperatures ranging from 800 to 1600 degrees C at different oxygen fugacity con-ditions (FMQ -5.6 to FMQ -0.3), either with 5 wt% CH4 + H2O or 5 wt% H2O added. Our results show that under reducing conditions (FMQ -5.6 or IW -0.7), the solidi of both eclogite and lherzolite with COH fluids are about 200 degrees C lower than the anhydrous solidi, but 100 degrees C higher than those under oxidizing conditions with 5 wt% H2O. The mineral chemistry of residual solid phases in both systems depends on oxygen fugacity (fO2). The stability of clinopyroxene at the solidus of lherzolite under reducing conditions is significantly greater than its stability under oxidizing conditions, whereas garnet is only stable during the partial melting of eclogite at low fO2. The composition of partial melts of lherzolite with 5 wt% CH4 + H2O under reducing conditions at low pressures is quartz normative rather than olivine normative. The higher-temperature solidi and phase relations under reducing conditions indicate that, if Archean mantle was more reduced than the modern mantle, komatiite could be formed under reducing conditions with no need for deep melting or the presence of abundant water. Further, our experiments indicate that low fO2 favors the precipitation of graphite or diamond, so a large amount of diamond or graphite could have accumulated in the Earth's deep mantle and the Martian mantle.

语种英语
内容类型期刊论文
版本出版稿
源URL[http://ir.idsse.ac.cn/handle/183446/9984]  
专题深海科学研究部_深海极端环境模拟研究实验室
通讯作者Zairong Liu
作者单位1.Institut für Mineralogie, Westf¨alische Wilhelms-Universit¨at Münster
2.CAS Key Laboratory of Experimental Study under Deep-sea Extreme Conditions, Institute of Deep-sea Science and Engineering, Chinese Academy of Sciences
3.Australian Research Council Centre of Excellence for Core to Crust Fluid Systems (CCFS), School of Natural Sciences, Macquarie University
推荐引用方式
GB/T 7714
Zairong Liu,Arno Rohrbach,Carla Tiraboschi,et al. The effect of COH fluids on partial melting of eclogite and lherzolite under moderately oxidizing and reducing conditions[J]. Chemical Geology,2023,616(2023):121219.
APA Zairong Liu,Arno Rohrbach,Carla Tiraboschi,Stephen F. Foley,Jasper Berndt,&Stephan Klemme.(2023).The effect of COH fluids on partial melting of eclogite and lherzolite under moderately oxidizing and reducing conditions.Chemical Geology,616(2023),121219.
MLA Zairong Liu,et al."The effect of COH fluids on partial melting of eclogite and lherzolite under moderately oxidizing and reducing conditions".Chemical Geology 616.2023(2023):121219.
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