2D lamellar membrane with nanochannels synthesized by bottom-up assembly approach for the superior photocatalytic hydrogen evolution

doi:10.1016/j.rser.2022.112767

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	2D lamellar membrane with nanochannels synthesized by bottom-up assembly approach for the superior photocatalytic hydrogen evolution
	W. M. Zhou; Y. T. Wu; H. Q. Huang; M. X. Zhang; X. H. Sun; Z. Q. Wang; F. Zhao; H. Y. Zhang; T. F. Xie; M. An
刊名	Renewable & Sustainable Energy Reviews
	2022
卷号	168 页码:11
ISSN号	1364-0321
DOI	10.1016/j.rser.2022.112767
英文摘要	Designing nanoscale photocatalysts to improve photocatalytic efficiency is a popular research topic. However, for wide application and friendly environment, achieving good dispersion and multiple recycling of photo -catalysts at the nanoscale remains challenging. Herein, a general bottom-up assembly method is proposed for designing a class of two-dimensional lamellar membranes (2DLMs) for photocatalytic applications. A bismuth oxychloride (BiOCl) nanosheet (BN) was used as a demo photocatalyst to construct a 2DLM via self-stacking. The designed BiOCl membrane (BM) exhibited excellent physical properties including flexibility, mechanical strength (tensile strength = 15.75 MPa, fracture strain = 0.056%), and translucence, as well as superior photocatalytic performance with excellent recycling stability and reusability. The photocatalytic hydrogen evolution perfor-mance of BM was 2.5-fold that of BN particles dispersed in an aqueous solution. Further theoretical calculations revealed that a BM with appropriately sized nanochannels can accelerate water transport, and the main hori-zontal channel size of the BM (3.13 nm) is very close to the size of the ideal water transport nanochannel. Furthermore, the confined internal space reduces the number of hydrogen bonds for water molecules within the nanochannels, thereby enhancing the interfacial reaction rate and photocatalytic efficiency. This study presents a simple bottom-up assembly method to design photocatalysts with further improved performance.
URL标识	查看原文
语种	英语
内容类型	期刊论文
源URL	[http://ir.ciomp.ac.cn/handle/181722/66365]
专题	中国科学院长春光学精密机械与物理研究所
推荐引用方式 GB/T 7714	W. M. Zhou,Y. T. Wu,H. Q. Huang,et al. 2D lamellar membrane with nanochannels synthesized by bottom-up assembly approach for the superior photocatalytic hydrogen evolution[J]. Renewable & Sustainable Energy Reviews,2022,168:11.
APA	W. M. Zhou.,Y. T. Wu.,H. Q. Huang.,M. X. Zhang.,X. H. Sun.,...&L. W. Wang and Z. H. Yuan.(2022).2D lamellar membrane with nanochannels synthesized by bottom-up assembly approach for the superior photocatalytic hydrogen evolution.Renewable & Sustainable Energy Reviews,168,11.
MLA	W. M. Zhou,et al."2D lamellar membrane with nanochannels synthesized by bottom-up assembly approach for the superior photocatalytic hydrogen evolution".Renewable & Sustainable Energy Reviews 168(2022):11.