Incipient reddening of Ordovician carbonates: The origin and geochemistry of yellow and pink colouration in limestones
Babek, Ondrej4; Kumpan, Tomas3; Li, Wenjie(李文杰)2; Hola, Marketa1; Simicek, Daniel4; Kapusta, Jaroslav4
刊名SEDIMENTARY GEOLOGY
2022-10-01
卷号440页码:16
关键词Ordovician Microbial activity Early diagenesis Redox cycling Geochemistry Marine red beds
ISSN号0037-0738
DOI10.1016/j.sedgeo.2022.106262
英文摘要

Red colouring in marine red beds (MRB) is commonly attributed to deposition and early diagenesis under specific redox conditions. Therefore, the MRB can be considered time-specific facies. However, since red colouring is a sub-jective criterion, it is difficult to establish a colour limit for the MRB in the scale from grey to yellow, orange, pink to red. Using spectral reflectance, carbonate petrology, bulk-rock and in-situ geochemistry data from three sections of Ordovician orthoceratite carbonates of South China, we addressed the question whether the incipient reddening in the pink carbonates was associated with similar redox changes and palaeoceanographic conditions like in the MRB. The yellowish grey to greyish orange pink (Munsell Rock Colour Chart) carbonates with low concentrations of he-matite (< 0.01 %) are transitional from goethite-bearing grey to hematite-enriched true MRB. The red-coloured skel-etal interiors, microstromatolites, nodules and filamentous microborings suggest an extensive microbial activity which was accompanied by precipitation of authigenic aluminosilicates (clays). We hypothesize that the microbial clay precipitation is an important intermediate step in Fe transformation from its primary sources to hematite in the MRB. The carbonate deposition was followed by early diagenetic, shallow-subsurface REE fractionation, and Fe\\Mn (+Mo, U and V) redox cycling along microbially controlled redox microgradients. The geochemical redox signature of the pink carbonates is very similar to the MRBs of Devonian and Ordovician age. They were deposited under sim-ilar palaeoenvironmental conditions on a deeper shelf inhabited by skeletal heterotrophs, with reduced rates of or-ganic matter burial and slow sedimentation rates. The sedimentation of the pink carbonates and MRBs seem to randomly coincide with the coeval global sea-level changes and delta 13Ccarb fluctuations suggesting that the local controls of sediment colour override the global ones.(c) 2022 Elsevier B.V. All rights reserved.

资助项目Czech Science Foundation (GACR)[19-17435S]
WOS关键词RARE-EARTH-ELEMENTS ; ROSSO-AMMONITICO-VERONESE ; OCEANIC RED BEDS ; SOUTH CHINA ; YANGTZE REGION ; TRACE-METALS ; ISOTOPE STRATIGRAPHY ; PELAGIC LIMESTONES ; SEDIMENTARY-ROCKS ; CERIUM ANOMALIES
WOS研究方向Geology
语种英语
出版者ELSEVIER
WOS记录号WOS:000872548200001
资助机构Czech Science Foundation (GACR)
内容类型期刊论文
源URL[http://ir.nigpas.ac.cn/handle/332004/41369]  
专题中国科学院南京地质古生物研究所
通讯作者Babek, Ondrej
作者单位1.Masaryk Univ, Dept Chem, Kamenice 753-5, Brno 62500, Czech Republic
2.Chinese Acad Sci, Nanjing Inst Geol & Palaeontol, State Key Lab Palaeobiol & Stratig, Nanjing 210008, Peoples R China
3.Masaryk Univ, Dept Geol Sci, Kotlarska 2, Brno 61137, Czech Republic
4.Palacky Univ, Dept Geol, 17 Listopadu 12, Olomouc 77146, Czech Republic
推荐引用方式
GB/T 7714
Babek, Ondrej,Kumpan, Tomas,Li, Wenjie,et al. Incipient reddening of Ordovician carbonates: The origin and geochemistry of yellow and pink colouration in limestones[J]. SEDIMENTARY GEOLOGY,2022,440:16.
APA Babek, Ondrej,Kumpan, Tomas,Li, Wenjie,Hola, Marketa,Simicek, Daniel,&Kapusta, Jaroslav.(2022).Incipient reddening of Ordovician carbonates: The origin and geochemistry of yellow and pink colouration in limestones.SEDIMENTARY GEOLOGY,440,16.
MLA Babek, Ondrej,et al."Incipient reddening of Ordovician carbonates: The origin and geochemistry of yellow and pink colouration in limestones".SEDIMENTARY GEOLOGY 440(2022):16.
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