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Kinetics of Copper Dissolution in Liquid Tin by Direct Current
Sun, Xuemin; Yu, Weiyuan; Wu, Baolei; Yang, Guoqing; Liu, Yun
刊名Xiyou Jinshu Cailiao Yu Gongcheng/Rare Metal Materials and Engineering
2020-10-01
卷号49期号:10页码:3425-3432
关键词Activation energy Copper Liquids Rate constants Tin Comsol multiphysics Copper dissolution Direct current Dissolution kinetics Dissolution rates Effective charge Immersion method Temperature range
ISSN号1002185X
英文摘要The dissolution kinetics of copper in liquid tin in the temperature range of 513~573 K were investigated under the influence of a DC current by immersion method. After dissolution, the dissolution thickness and the thickness of IMC layer at Sn/Cu interface were measured and the dissolution activation energy and effective charge Z* were calculated. The temperature distribution and flow field of the liquid tin caused by the current were simulated by Comsol Multiphysics. It is found that the current has a marked effect on the dissolution rate constant. Correspondingly, the application of the current significantly decreases the activation energy of dissolution. Similarly, the direction of the DC current has an effect on dissolution of copper and the growth of IMC. When the electronic flow is in the direction of dissolution, a further increase in dissolution and a decrease in growth of IMC layer are observed which are attributed to electromigration. When the current density is 240 A/cm2, the effective charge Z* decreases with the increase of temperature. © 2020, Science Press. All right reserved.
WOS研究方向Materials Science ; Metallurgy & Metallurgical Engineering
语种中文
出版者Science Press
WOS记录号WOS:000588490000020
内容类型期刊论文
源URL[http://ir.lut.edu.cn/handle/2XXMBERH/150819]  
专题实验室建设与管理处
作者单位State Key Laboratory of Advanced Processing and Recycling on Non-Ferrous Metals, Lanzhou University of Technology, Lanzhou; 730050, China
推荐引用方式
GB/T 7714
Sun, Xuemin,Yu, Weiyuan,Wu, Baolei,et al. Kinetics of Copper Dissolution in Liquid Tin by Direct Current[J]. Xiyou Jinshu Cailiao Yu Gongcheng/Rare Metal Materials and Engineering,2020,49(10):3425-3432.
APA Sun, Xuemin,Yu, Weiyuan,Wu, Baolei,Yang, Guoqing,&Liu, Yun.(2020).Kinetics of Copper Dissolution in Liquid Tin by Direct Current.Xiyou Jinshu Cailiao Yu Gongcheng/Rare Metal Materials and Engineering,49(10),3425-3432.
MLA Sun, Xuemin,et al."Kinetics of Copper Dissolution in Liquid Tin by Direct Current".Xiyou Jinshu Cailiao Yu Gongcheng/Rare Metal Materials and Engineering 49.10(2020):3425-3432.
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