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Redox molecule Alizarin red S anchored on biomass-derived porous carbon for enhanced supercapacitive performance
Bao, Yuanhai1,2; Xu, Hui1,2; Chen, Pengdong1,2; Zhu, Yuanqiang1,2; Zuo, Shasha1,2; Kong, Xiuqin1,2; Chen, Yong1,2
刊名NEW JOURNAL OF CHEMISTRY
2022-08-01
卷号46期号:30页码:14711-14723
ISSN号1144-0546
DOI10.1039/d2nj02394f
英文摘要Benefiting from its large specific surface area and hierarchical pore structure, biomass-derived porous carbon is widely used as an electrode material for energy storage devices. In this research, ginkgo leaves are used as a precursor and KOH as an activator to prepare porous carbon (KGL). The anthraquinone-type anionic dye molecule Alizarin red S (ARS) is anchored on porous carbon via two adsorption methods. ARS plays a crucial role in enhancing the electrochemical properties. KGL has larger adsorption capacity for ARS through electric field assisted adsorption compared with physical adsorption and more favorable electrochemical performance. KGL/ARS exhibits superior specific capacitance and rate performance because the redox reaction of ARS and porous carbon provides a stable conductive scaffold. The KGL/ARS-E5 electrode possesses a specific capacitance of 638.2 F g(-1) at 1 A g(-1) and the capacitance retention reaches 77.9% at 10 A g(-1). The assembled asymmetric supercapacitor exhibits an energy density of 24.8 W h kg(-1) at a power density of 801.4 W kg(-1), and the capacitance retention of the device is 93.5% after 10 000 cycles. The research provides a novel method to achieve a combination of porous carbon and redox-enhanced materials as the electrode for supercapacitors and realizes the recycling of carbonous adsorbents containing the redox species.
WOS研究方向Chemistry
语种英语
出版者ROYAL SOC CHEMISTRY
WOS记录号WOS:000825707100001
内容类型期刊论文
源URL[http://ir.lut.edu.cn/handle/2XXMBERH/159444]  
专题石油化工学院
作者单位1.Lanzhou Univ Technol, Coll Petrochem Engn, Lanzhou, Peoples R China;
2.Key Lab Low Carbon Energy & Chem Engn Gansu Prov, Lanzhou, Peoples R China
推荐引用方式
GB/T 7714
Bao, Yuanhai,Xu, Hui,Chen, Pengdong,et al. Redox molecule Alizarin red S anchored on biomass-derived porous carbon for enhanced supercapacitive performance[J]. NEW JOURNAL OF CHEMISTRY,2022,46(30):14711-14723.
APA Bao, Yuanhai.,Xu, Hui.,Chen, Pengdong.,Zhu, Yuanqiang.,Zuo, Shasha.,...&Chen, Yong.(2022).Redox molecule Alizarin red S anchored on biomass-derived porous carbon for enhanced supercapacitive performance.NEW JOURNAL OF CHEMISTRY,46(30),14711-14723.
MLA Bao, Yuanhai,et al."Redox molecule Alizarin red S anchored on biomass-derived porous carbon for enhanced supercapacitive performance".NEW JOURNAL OF CHEMISTRY 46.30(2022):14711-14723.
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