Study on preparation and property of doped conductive polyaniline(PANI) base on grey system theory

doi:10.3969/j.issn.1001-9731.2013.20.003

CORC > 兰州理工大学 > 兰州理工大学 > 石油化工学院

	Study on preparation and property of doped conductive polyaniline(PANI) base on grey system theory
	Feng, Hui-Xia; Lu, Hua-Tao; Liu, Sheng-Li; Wang, Yi; Zhang, De-Yi
刊名	Gongneng Cailiao/Journal of Functional Materials
	2013-10-30
卷号	44 期号:20 页码:2919-2922
关键词	Doping (additives) Oxidants Polymerization Sulfamic acid System theory Application examples Chemical oxidation polymerization Conductive polyaniline Experiment data Grey relational analysis Grey system theory Molar ratio Verhulst model
ISSN号	10019731
DOI	10.3969/j.issn.1001-9731.2013.20.003
英文摘要	With aniline(An) as monomer, sulfamic acid(SA) as dopant, ammonium persulfate(APS) as oxidant, prepared doped conductive polyaniline(PANI) via chemical oxidation polymerization. We researched the effect of molar ratio of An and dopant, An and oxidant, and reaction time to the conductivity of PANI. The conductivity of PANI was to 0.87S/cm, when reaction time was 6h and n(An):n(SA):n(APS) =1:6:0.4. Furthermore, the extents of factors affecting the conductivity of PANI were analyzed quantitatively using the grey relational analysis with the order of the dopant, oxidant, reaction time. And basing on grey prediction theory, the grey discrete Verhulst model of the conductivity of PANI was built with the sulfamic acid(SA) addition as base quantity by dealing with the original experiment data. The conductivity of PANI was predicted at the different sulfamic acid(SA) addition. The average accuracy was 97.25%.The application examples showed that these new methods had higher accuracy, therefore the conductivity of PANI forecasting based on grey system theory was feasible.
语种	中文
出版者	Journal of Functional Materials, P.O. Box 1512, Chongqing, 630700, China
内容类型	期刊论文
源URL	[http://ir.lut.edu.cn/handle/2XXMBERH/112904]
专题	石油化工学院教务处（创新创业学院）
作者单位	School of Petrochemical Engineering, Lanzhou University of Technology, Lanzhou 730050, China
推荐引用方式 GB/T 7714	Feng, Hui-Xia,Lu, Hua-Tao,Liu, Sheng-Li,et al. Study on preparation and property of doped conductive polyaniline(PANI) base on grey system theory[J]. Gongneng Cailiao/Journal of Functional Materials,2013,44(20):2919-2922.
APA	Feng, Hui-Xia,Lu, Hua-Tao,Liu, Sheng-Li,Wang, Yi,&Zhang, De-Yi.(2013).Study on preparation and property of doped conductive polyaniline(PANI) base on grey system theory.Gongneng Cailiao/Journal of Functional Materials,44(20),2919-2922.
MLA	Feng, Hui-Xia,et al."Study on preparation and property of doped conductive polyaniline(PANI) base on grey system theory".Gongneng Cailiao/Journal of Functional Materials 44.20(2013):2919-2922.