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Preparation and electrochemical properties of self-doped nitrogen porous carbon derived from Zn-MOFs
Zhang, Dongqiang; Zhang, Chi; Wang, Qian; Li, Shuai; Zhao, Xia; Luo, Heming
刊名CARBON LETTERS
2019-10-21
卷号30期号:3页码:315-324
关键词Metal organic framework Hydrothermal method Self-doped nitrogen porous carbon Electrochemical properties Supercapacitor
ISSN号1976-4251
DOI10.1007/s42823-019-00100-5
英文摘要Metal-organic frameworks (MOFs) are network-like frameworks composed of transition metals and organic ligands containing oxygen or nitrogen. Because of its highly controllable composition and ordered porous structure, it has broad application prospects in the field of material synthesis. In this work, Zn-4(PYDC)(4)(DMF)(2)center dot 3DMF (ZPD) was synthesized via a hydrothermal method. Self-doped nitrogen porous carbon ZPDC-T was then prepared by one-step carbonization. The results show that the self-doped nitrogen porous carbon ZPDC-850 has a micro/mesoporous structure with a specific surface area of 1520 m(2) g(-1) and a nitrogen content of 6.47%. When a current density is 1.0 A g(-1), its specific capacitance is 265.1 F g(-1). After 5000 times of constant current charging and discharging, the capacitance retention rate was 79.2%. Thus, self-doped nitrogen porous carbon ZPDC-850 exhibits excellent electrochemical properties and good cyclic stability. Therefore, the self-doped nitrogen porous carbon derived from MOFs can be a promising electrode material for supercapacitors.
资助项目National Nature Science Foundation of China[21667017][21666018]
WOS研究方向Chemistry ; Materials Science
语种英语
出版者SPRINGER JAPAN KK
WOS记录号WOS:000491833800002
状态已发表
内容类型期刊论文
源URL[http://ir.lut.edu.cn/handle/2XXMBERH/64205]  
专题石油化工学院
通讯作者Luo, Heming
作者单位Lanzhou Univ Technol, Sch Petrochem Engn, Lanzhou, Gansu, Peoples R China
推荐引用方式
GB/T 7714
Zhang, Dongqiang,Zhang, Chi,Wang, Qian,et al. Preparation and electrochemical properties of self-doped nitrogen porous carbon derived from Zn-MOFs[J]. CARBON LETTERS,2019,30(3):315-324.
APA Zhang, Dongqiang,Zhang, Chi,Wang, Qian,Li, Shuai,Zhao, Xia,&Luo, Heming.(2019).Preparation and electrochemical properties of self-doped nitrogen porous carbon derived from Zn-MOFs.CARBON LETTERS,30(3),315-324.
MLA Zhang, Dongqiang,et al."Preparation and electrochemical properties of self-doped nitrogen porous carbon derived from Zn-MOFs".CARBON LETTERS 30.3(2019):315-324.
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