Pd catalyst supported on a chitosan-functionalized large-area 3D reduced graphene oxide for formic acid electrooxidation reaction

doi:10.1039/c3ta10214a

CORC > 兰州理工大学 > 兰州理工大学 > 石油化工学院

	Pd catalyst supported on a chitosan-functionalized large-area 3D reduced graphene oxide for formic acid electrooxidation reaction
	Wang, Yi 2,3; Liu, Huili 3,4; Wang, Li 1,3; Wang, Haibo 2; Du, Xuan 3; Wang, Fang 3; Qi, Tao 3; Lee, Jong-Min 2; Wang, Xin 2
刊名	JOURNAL OF MATERIALS CHEMISTRY A
	2013
卷号	1 期号:23 页码:6839-6848
关键词	Carbon black Catalyst activity Chitosan Electronic properties Electrooxidation Formic acid Formic acid fuel cells (FAFC) Gas adsorption Graphene Palladium Reduced Graphene Oxide Scanning electron microscopy Catalyst support material Direct formic acid fuel cells Electrocatalytic activity Formic acid electrooxidation Peak current density Reduced graphene oxides (RGO) Threedimensional (3-d) Two Dimensional (2 D)
ISSN号	2050-7488
DOI	10.1039/c3ta10214a
英文摘要	A large-area three-dimensional (3D) reduced graphene oxide (TRGO) material was obtained by facile heat treatment of a two-dimensional (2D) reduced graphene oxide (RGO) material. X-ray diffraction (XRD), scanning electron microscopy (SEM) and nitrogen adsorption results reveal that the new material is composed of small and fluffy graphene nanosheets, with many graphene arrays as well as 3D interconnected macropores and mesopores in some local positions, and possesses an ultrahigh specific surface area (>1000 m(2) g(-1)) and large pore volume. The material was used to support a Pd catalyst for formic acid electrooxidation, demonstrating a much better electrocatalytic activity in terms of the onset potential and peak current density (seven times larger) than that of conventional carbon black, the most popular catalyst support. To tailor the electronic properties, the TRGO material was further functionalized with chitosan (CS). Compared to the Pd loaded on TRGO, Pd nanoparticles supported on the CS-functionalized TRGO show a better catalytic activity and good stability. This work provides a promising catalyst support material for direct formic acid fuel cells.
资助项目	National Research Foundation, Singapore[2009 NRF-CRP 001-032]
WOS研究方向	Chemistry ; Energy & Fuels ; Materials Science
语种	英语
出版者	ROYAL SOC CHEMISTRY
WOS记录号	WOS:000319272800018
状态	已发表
内容类型	期刊论文
源URL	[http://119.78.100.223/handle/2XXMBERH/34800]
专题	石油化工学院
通讯作者	Wang, Yi
作者单位	1.Lanzhou Univ Technol, Coll Petrochem Technol, Lanzhou 730050, Peoples R China 2.Nanyang Technol Univ, Sch Chem & Biomed Engn, Singapore 637459, Singapore 3.Chinese Acad Sci, Inst Proc Engn, Natl Engn Lab Hydromet Cleaner Prod Technol, Beijing 100190, Peoples R China 4.China West Normal Univ, Coll Chem & Chem Engn, Nanchong 637000, Peoples R China
推荐引用方式 GB/T 7714	Wang, Yi,Liu, Huili,Wang, Li,et al. Pd catalyst supported on a chitosan-functionalized large-area 3D reduced graphene oxide for formic acid electrooxidation reaction[J]. JOURNAL OF MATERIALS CHEMISTRY A,2013,1(23):6839-6848.
APA	Wang, Yi.,Liu, Huili.,Wang, Li.,Wang, Haibo.,Du, Xuan.,...&Wang, Xin.(2013).Pd catalyst supported on a chitosan-functionalized large-area 3D reduced graphene oxide for formic acid electrooxidation reaction.JOURNAL OF MATERIALS CHEMISTRY A,1(23),6839-6848.
MLA	Wang, Yi,et al."Pd catalyst supported on a chitosan-functionalized large-area 3D reduced graphene oxide for formic acid electrooxidation reaction".JOURNAL OF MATERIALS CHEMISTRY A 1.23(2013):6839-6848.