Organic additives enhance Fenton treatment of nitrobenzene at near-neutral pH | |
Xie, Gang1,2,3; Zhou, Lincheng1,3; Gao, Weijie1,3; Li, Yanfeng1,3 | |
刊名 | ENVIRONMENTAL SCIENCE AND POLLUTION RESEARCH |
2015-05 | |
卷号 | 22期号:9页码:7082-7092 |
关键词 | Fenton Organic additives Advanced oxidation processes (AOPs) Nitrobenzene |
ISSN号 | 0944-1344 |
DOI | 10.1007/s11356-014-3809-4 |
英文摘要 | Nitrobenzene (NB) is considered a toxic and potential carcinogen. Continuous contamination has resulted in an urgent need for remediation. Fenton reagent provides an advanced oxidation process that is capable of remediating recalcitrant nitroaromatic compounds, such as NB. However, one drawback of Fenton chemistry is that the reaction requires acidic pH to prevent precipitation of iron. Our studies have investigated Fenton conversion of NB at near-neutral pH with several organic additives: beta-cyclodextrin (beta-CD), hydroxypropyl-beta-cyclodextrin (HPCD), carboxymethyl-beta-cyclodextrin (CMCD), and polyethylene glycol (molecular weight (MW) = 200, 400, and 600) for developing a process for treating NB-contaminated waters. The main factors influencing NB conversion, such as iron concentration, hydroxyl radicals (center dot OH) scavengers, and kinds or concentration of organic additives, were examined. Meanwhile, the reactive mechanisms and kinetics were investigated for Fenton conversion of NB. The results show that organic additives for Fenton process should be a good alternative for the advanced treatment of NB at near-neutral pH. |
资助项目 | Sustentation Program of Science and Technology of China[2006BRD01B03] |
WOS研究方向 | Environmental Sciences & Ecology |
语种 | 英语 |
出版者 | SPRINGER HEIDELBERG |
WOS记录号 | WOS:000353046600065 |
状态 | 已发表 |
内容类型 | 期刊论文 |
源URL | [http://119.78.100.223/handle/2XXMBERH/34063] |
专题 | 石油化工学院 |
通讯作者 | Li, Yanfeng |
作者单位 | 1.Lanzhou Univ, Inst Biochem Engn & Environm Technol, Coll Resources & Environm, State Key Lab Appl Organ Chem, Lanzhou 730000, Peoples R China 2.Lanzhou Univ Technol, Coll Petrochem Engn, Ctr Forecasting & Anal, Lanzhou 730050, Peoples R China 3.Lanzhou Univ, Inst Biochem Engn & Environm Technol, Coll Chem & Chem Engn, State Key Lab Appl Organ Chem, Lanzhou 730000, Peoples R China |
推荐引用方式 GB/T 7714 | Xie, Gang,Zhou, Lincheng,Gao, Weijie,et al. Organic additives enhance Fenton treatment of nitrobenzene at near-neutral pH[J]. ENVIRONMENTAL SCIENCE AND POLLUTION RESEARCH,2015,22(9):7082-7092. |
APA | Xie, Gang,Zhou, Lincheng,Gao, Weijie,&Li, Yanfeng.(2015).Organic additives enhance Fenton treatment of nitrobenzene at near-neutral pH.ENVIRONMENTAL SCIENCE AND POLLUTION RESEARCH,22(9),7082-7092. |
MLA | Xie, Gang,et al."Organic additives enhance Fenton treatment of nitrobenzene at near-neutral pH".ENVIRONMENTAL SCIENCE AND POLLUTION RESEARCH 22.9(2015):7082-7092. |
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