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Organic additives enhance Fenton treatment of nitrobenzene at near-neutral pH
Xie, Gang1,2,3; Zhou, Lincheng1,3; Gao, Weijie1,3; Li, Yanfeng1,3
刊名ENVIRONMENTAL SCIENCE AND POLLUTION RESEARCH
2015-05
卷号22期号:9页码:7082-7092
关键词Fenton Organic additives Advanced oxidation processes (AOPs) Nitrobenzene
ISSN号0944-1344
DOI10.1007/s11356-014-3809-4
英文摘要Nitrobenzene (NB) is considered a toxic and potential carcinogen. Continuous contamination has resulted in an urgent need for remediation. Fenton reagent provides an advanced oxidation process that is capable of remediating recalcitrant nitroaromatic compounds, such as NB. However, one drawback of Fenton chemistry is that the reaction requires acidic pH to prevent precipitation of iron. Our studies have investigated Fenton conversion of NB at near-neutral pH with several organic additives: beta-cyclodextrin (beta-CD), hydroxypropyl-beta-cyclodextrin (HPCD), carboxymethyl-beta-cyclodextrin (CMCD), and polyethylene glycol (molecular weight (MW) = 200, 400, and 600) for developing a process for treating NB-contaminated waters. The main factors influencing NB conversion, such as iron concentration, hydroxyl radicals (center dot OH) scavengers, and kinds or concentration of organic additives, were examined. Meanwhile, the reactive mechanisms and kinetics were investigated for Fenton conversion of NB. The results show that organic additives for Fenton process should be a good alternative for the advanced treatment of NB at near-neutral pH.
资助项目Sustentation Program of Science and Technology of China[2006BRD01B03]
WOS研究方向Environmental Sciences & Ecology
语种英语
出版者SPRINGER HEIDELBERG
WOS记录号WOS:000353046600065
状态已发表
内容类型期刊论文
源URL[http://119.78.100.223/handle/2XXMBERH/34063]  
专题石油化工学院
通讯作者Li, Yanfeng
作者单位1.Lanzhou Univ, Inst Biochem Engn & Environm Technol, Coll Resources & Environm, State Key Lab Appl Organ Chem, Lanzhou 730000, Peoples R China
2.Lanzhou Univ Technol, Coll Petrochem Engn, Ctr Forecasting & Anal, Lanzhou 730050, Peoples R China
3.Lanzhou Univ, Inst Biochem Engn & Environm Technol, Coll Chem & Chem Engn, State Key Lab Appl Organ Chem, Lanzhou 730000, Peoples R China
推荐引用方式
GB/T 7714
Xie, Gang,Zhou, Lincheng,Gao, Weijie,et al. Organic additives enhance Fenton treatment of nitrobenzene at near-neutral pH[J]. ENVIRONMENTAL SCIENCE AND POLLUTION RESEARCH,2015,22(9):7082-7092.
APA Xie, Gang,Zhou, Lincheng,Gao, Weijie,&Li, Yanfeng.(2015).Organic additives enhance Fenton treatment of nitrobenzene at near-neutral pH.ENVIRONMENTAL SCIENCE AND POLLUTION RESEARCH,22(9),7082-7092.
MLA Xie, Gang,et al."Organic additives enhance Fenton treatment of nitrobenzene at near-neutral pH".ENVIRONMENTAL SCIENCE AND POLLUTION RESEARCH 22.9(2015):7082-7092.
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