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Highly efficient synthesis of LTA-type aluminophosphate molecular sieve by improved ionothermal method
Zhao, Xinhong1,2; Zhao, Jiangbo1; Chiang, Chang-Yang2; Li, Zhengshan1; Zhao, Yu1; Zhou, Wuzong2
刊名NEW JOURNAL OF CHEMISTRY
2016
卷号40期号:3页码:2444-2450
ISSN号1144-0546
DOI10.1039/c5nj03006d
英文摘要An LTA-type aluminophosphate molecular sieve has been successfully synthesized by an improved ionothermal method from a gel containing low-dosage ionic liquids. The optimum synthetic conditions of this material are refined. The resultant LTA molecular sieves were characterized by XRD, SEM, TG-DTA, CHN elemental analysis, solution C-13 NMR, EDX, TEM and N-2 physisorption. The composition of the resulting LTA-type molecular sieves is determined to be (Al12P12O48)(C4H9NO)(2)(C8H15N2+)(2)(F)(2), for which morpholine together with 1-butyl-3-methylimidazolium cations act as the structure-directing agent. The high zeolite yield, as well as the high specific surface area and micropore volume for the calcined LTA-type materials, imply that these zeolitic materials have a high potential in applications.
资助项目Engineering and Physical Sciences Research Council[EP/F019580/1]
WOS研究方向Chemistry
语种英语
出版者ROYAL SOC CHEMISTRY
WOS记录号WOS:000372425600068
状态已发表
内容类型期刊论文
源URL[http://119.78.100.223/handle/2XXMBERH/33848]  
专题石油化工学院
通讯作者Zhao, Xinhong
作者单位1.Lanzhou Univ Technol, Sch Petrochem Engn, Lanzhou 730050, Peoples R China
2.Univ St Andrews, Sch Chem, EaStChem, St Andrews KY16 9ST, Fife, Scotland
推荐引用方式
GB/T 7714
Zhao, Xinhong,Zhao, Jiangbo,Chiang, Chang-Yang,et al. Highly efficient synthesis of LTA-type aluminophosphate molecular sieve by improved ionothermal method[J]. NEW JOURNAL OF CHEMISTRY,2016,40(3):2444-2450.
APA Zhao, Xinhong,Zhao, Jiangbo,Chiang, Chang-Yang,Li, Zhengshan,Zhao, Yu,&Zhou, Wuzong.(2016).Highly efficient synthesis of LTA-type aluminophosphate molecular sieve by improved ionothermal method.NEW JOURNAL OF CHEMISTRY,40(3),2444-2450.
MLA Zhao, Xinhong,et al."Highly efficient synthesis of LTA-type aluminophosphate molecular sieve by improved ionothermal method".NEW JOURNAL OF CHEMISTRY 40.3(2016):2444-2450.
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