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KOH-activated nitrogen doped porous carbon nanowires with superior performance in supercapacitors
Wang, Bin2; Qiu, Jianhui1,2; Feng, Huixia3; Sakai, Eiichi2; Komiyama, Takao2
刊名ELECTROCHIMICA ACTA
2016-02
卷号190页码:229-239
关键词Nitrogen doped carbon nanowires KOH activation supercapacitors
ISSN号0013-4686
DOI10.1016/j.electacta.2016.01.038
英文摘要Nitrogen-doped porous carbon nanowires were prepared by KOH activation of nitrogen doped carbon nanowires derived from direct carbonization of polypyrrole nanowires. The porous structure and nitrogen content were closely related to the mass ratio of KOH and carbon nanowires. The resultant nanowires demonstrated the highest specific surface area (1642 m(2) g(-1)) and capacitance (291 F g(-1) at the current density of 1 Ag-1 in three-electrode systems), when the mass ratio of KOH and nitrogen doped carbon nanowires reached 2. It also exhibited the excellent high rate performance and good cycle stability (94.8% capacitance retention after 5000 cycles) in three-electrode systems. High energy density (21.9 Wh kg(-1) at a current density of 0.4 A g(-1) in 0-1.6 V) and good cycle stability (the capacitance retention of 98.1% over 5000 cycles) were shown in symmetric two-electrode systems. These excellent electrochemical performances could be attributed to the high surface area, unique micro/meso/macroporous structure, and optimized nitrogen content. (C) 2016 Elsevier Ltd. All rights reserved.
资助项目Fundamental Research Funds for the Universities of Gansu[1105ZTC136]
WOS研究方向Electrochemistry
语种英语
出版者PERGAMON-ELSEVIER SCIENCE LTD
WOS记录号WOS:000371141500028
状态已发表
内容类型期刊论文
源URL[http://119.78.100.223/handle/2XXMBERH/33792]  
专题石油化工学院
教务处(创新创业学院)
通讯作者Qiu, Jianhui
作者单位1.Chongqing Univ, Coll Aerosp Engn, Shazheng Rd, Chongqing 400030, Peoples R China
2.Akita Prefectural Univ, Fac Syst Engn, Dept Machine Intelligence & Syst Engn, Akita 0150055, Japan
3.Lanzhou Univ Technol, Coll Petrochem Technol, Lanzhou 730050, Peoples R China
推荐引用方式
GB/T 7714
Wang, Bin,Qiu, Jianhui,Feng, Huixia,et al. KOH-activated nitrogen doped porous carbon nanowires with superior performance in supercapacitors[J]. ELECTROCHIMICA ACTA,2016,190:229-239.
APA Wang, Bin,Qiu, Jianhui,Feng, Huixia,Sakai, Eiichi,&Komiyama, Takao.(2016).KOH-activated nitrogen doped porous carbon nanowires with superior performance in supercapacitors.ELECTROCHIMICA ACTA,190,229-239.
MLA Wang, Bin,et al."KOH-activated nitrogen doped porous carbon nanowires with superior performance in supercapacitors".ELECTROCHIMICA ACTA 190(2016):229-239.
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