Durable, transparent, and hot liquid repelling superamphiphobic coatings from polysiloxane-modified multiwalled carbon nanotubes | |
Zhang, Junping1; Yu, Bo1,2; Gao, Ziqian1; Li, Bucheng1; Zhao, Xia2 | |
刊名 | Langmuir
![]() |
2017 | |
卷号 | 33期号:2页码:510-518 |
关键词 | Coatings Durability High resolution transmission electron microscopy Hydrolysis Liquids Microstructure Nanotubes Scanning electron microscopy Silica Silicones Toluene Transparency X ray photoelectron spectroscopy High transparency Homogeneous suspensions Hydrolytic condensation Modified multi-walled carbon nanotubes Scanning electrons Silica nanotubes Surface chemical composition Surface microstructures |
ISSN号 | 07437463 |
DOI | 10.1021/acs.langmuir.6b04213 |
英文摘要 | Although encouraging progress in the field of superamphiphobic coatings has been obtained, the superamphiphobic coatings with high durability, transparency, and repellency to hot liquids are very rare. Here, durable, transparent, and hot liquid-repelling superamphiphobic coatings were successfully prepared using polysiloxane-modified multiwalled carbon nanotubes (MWCNTs@POS) as the templates. The hydrolytic condensation of nhexadecyltrimethoxysilane (HDTMS) and tetraethoxysilane on the surface of MWCNTs formed MWCNTs@POS, which are highly dispersible in toluene. The superamphiphobic coatings were prepared by spray-coating the homogeneous suspension of MWCNTs@POS in toluene onto glass slides, calcination in air to form the silica nanotubes (SNTs), and then modification with 1H,1H,2H,2Hperfluorodecyltrichlorosilane in dry toluene. The changes in the surface microstructure, surface chemical composition, and wettability were characterized by various techniques such as scanning electron microscopy, transmission electron microscopy, and X-ray photoelectron spectroscopy. It was found that the microstructures of the SNTs have great influences on superamphiphobicity and transparency of the coatings and can be regulated by the concentration of HDTMS and the diameter of MWCNTs. The SNTs with tunable wall thickness and diameter could be obtained using the method. The superamphiphobic coatings showed high contact angles and low sliding angles for various cool and hot liquids of different surface tensions. The superamphiphobic coatings also exhibited high transparency and comprehensive durability. © 2016 American Chemical Society. |
WOS研究方向 | Chemistry ; Materials Science |
语种 | 英语 |
出版者 | American Chemical Society |
WOS记录号 | WOS:000392457600008 |
状态 | 已发表 |
内容类型 | 期刊论文 |
源URL | [http://ir.lut.edu.cn/handle/2XXMBERH/114566] ![]() |
专题 | 电气工程与信息工程学院 石油化工学院 |
通讯作者 | Zhang, Junping |
作者单位 | 1.Chinese Acad Sci, Lanzhou Inst Chem Phys, Key Lab Clay Mineral Appl Res Gansu Prov, Lanzhou 730000, Peoples R China 2.Lanzhou Univ Technol, Coll Petrochem Engn, Dept Chem Engn, Lanzhou 730050, Peoples R China |
推荐引用方式 GB/T 7714 | Zhang, Junping,Yu, Bo,Gao, Ziqian,et al. Durable, transparent, and hot liquid repelling superamphiphobic coatings from polysiloxane-modified multiwalled carbon nanotubes[J]. Langmuir,2017,33(2):510-518. |
APA | Zhang, Junping,Yu, Bo,Gao, Ziqian,Li, Bucheng,&Zhao, Xia.(2017).Durable, transparent, and hot liquid repelling superamphiphobic coatings from polysiloxane-modified multiwalled carbon nanotubes.Langmuir,33(2),510-518. |
MLA | Zhang, Junping,et al."Durable, transparent, and hot liquid repelling superamphiphobic coatings from polysiloxane-modified multiwalled carbon nanotubes".Langmuir 33.2(2017):510-518. |
个性服务 |
查看访问统计 |
相关权益政策 |
暂无数据 |
收藏/分享 |
除非特别说明,本系统中所有内容都受版权保护,并保留所有权利。
修改评论