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Mesoporous carbons for supercapacitors obtained by the pyrolysis of block copolymers
Wang, Yong1; Kong, Ling-Bin1,2; Li, Xiao-Ming1; Ran, Fen1; Luo, Yong-Chun2; Kang, Long2
刊名Xinxing Tan Cailiao/New Carbon Materials
2015-08-01
卷号30期号:4页码:302-309
关键词Carbon Carbonization Electrolytes Energy storage Mesoporous materials Potassium hydroxide Pyrolysis Supercapacitor Aqueous electrolyte Cycle stability High power capability High specific capacitances High specific surface area Mesoporous carbon Porous structures Reversible addition-fragmentation chain transfer polymerization
ISSN号10078827
DOI10.1016/s1872-5805(15)60191-3
英文摘要Novel mesoporous carbons were prepared by the simple pyrolysis of block-copolymers, polyacrylonitrile-b-polystyrene-b-polyacrylonitrile (PAN-b-PS-b-PAN), in which PAN generates a carbon network and PS is released to form mesopores after pyrolysis. The block-copolymers were synthesized by reversible addition-fragmentation chain transfer (RAFT) polymerization and the molecular weight of each polymer block can be designed to tailor the porous structure of the mesoporous carbons. The carbons have high specific surface areas and a well-controlled mesopore size. The best mesoporous carbon has a high specific capacitance of 185 F·g-1 at 0.625 A·g-1 with a high power capability and a remarkable cycle stability in 2 mol/L KOH aqueous electrolyte. ©, 2015, Xinxing Tan Cailiao/New Carbon Materials. All right reserved.
WOS研究方向Materials Science
语种英语
出版者Institute of Metal Research Chinese Academy of Sciences
WOS记录号WOS:000361585300003
内容类型期刊论文
源URL[http://ir.lut.edu.cn/handle/2XXMBERH/150338]  
专题材料科学与工程学院
设计艺术学院
作者单位1.State Key Laboratory of Advanced Processing and Recycling of Nonferrous Metals, School of Materials Science and Engineering, Lanzhou University of Technology, Lanzhou; 730050, China;
2.School of Materials Science and Engineering, Lanzhou University of Technology, Lanzhou; 730050, China
推荐引用方式
GB/T 7714
Wang, Yong,Kong, Ling-Bin,Li, Xiao-Ming,et al. Mesoporous carbons for supercapacitors obtained by the pyrolysis of block copolymers[J]. Xinxing Tan Cailiao/New Carbon Materials,2015,30(4):302-309.
APA Wang, Yong,Kong, Ling-Bin,Li, Xiao-Ming,Ran, Fen,Luo, Yong-Chun,&Kang, Long.(2015).Mesoporous carbons for supercapacitors obtained by the pyrolysis of block copolymers.Xinxing Tan Cailiao/New Carbon Materials,30(4),302-309.
MLA Wang, Yong,et al."Mesoporous carbons for supercapacitors obtained by the pyrolysis of block copolymers".Xinxing Tan Cailiao/New Carbon Materials 30.4(2015):302-309.
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