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Preparation of poly(acrylic acid)-graphite oxide superabsorbent nanocomposites
Zhu, Zhao-Qi1; Sun, Han-Xue1; Qin, Xiao-Juan1; Jiang, Lei2; Pei, Chun-Juan1; Wang, Li1; Zeng, Ying-Qiu2; Wen, Shu-Hao2; La, Pei-Qing1; Li, An1
刊名JOURNAL OF MATERIALS CHEMISTRY
2012
卷号22期号:11页码:4811-4817
关键词Acrylic monomers Ammonium persulfate Carboxylic acids Graphene oxide Graphite Saline water Methylene bisacrylamide Poly(acrylic acid ) Polyacrylic acids Polymer networks Saline solutions Solution polymerization Water absorbency Water retention ability
ISSN号0959-9428
DOI10.1039/c2jm14210d
英文摘要Graphite oxide (GO) nanoplatelets with a thickness from 0.8 nm to 2 nm were prepared using a modified Hummers method. By employing GO nanoplatelets as nanofillers, poly(acrylic acid)-GO superabsorbent nanocomposites were synthesized by a facile solution polymerization of acrylic acid monomers using N,N'-methylenebisacrylamide as cross-linker and ammonium persulfate as initiator. The well-dispersed GO nanoplatelets in the polymer networks results in a significant improvement in absorbencies both in distilled water and saline solutions. With only a very low loading of GO in the superabsorbent nanocomposite, for example 0.073 wt%, its water absorbency reaches up to 508 g g(-1), which is nearly as twice that of the poly(acrylic acid) (PAA) superabsorbent. The superabsorbent nanocomposite also exhibits a superior water-retention ability compared with the control under the same conditions. Our study may provide a new way for the development of novel, GO-based superabsorbent nanocomposites with improved absorbency and may find a variety of useful applications.
资助项目National Natural Science Foundation of China[51164022]
WOS研究方向Chemistry ; Materials Science
语种英语
出版者ROYAL SOC CHEMISTRY
WOS记录号WOS:000300571400039
状态已发表
内容类型期刊论文
源URL[http://119.78.100.223/handle/2XXMBERH/34998]  
专题石油化工学院
材料科学与工程学院
通讯作者Li, An
作者单位1.Lanzhou Univ Technol, Key Lab Nonferrous Met Alloys & Proc, State Key Lab Gansu Adv Nonferrous Met Mat, Minist Educ,Coll Petrochem Technol, Lanzhou 730050, Peoples R China
2.Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Mol React Dynam, Dalian 116023, Peoples R China
推荐引用方式
GB/T 7714
Zhu, Zhao-Qi,Sun, Han-Xue,Qin, Xiao-Juan,et al. Preparation of poly(acrylic acid)-graphite oxide superabsorbent nanocomposites[J]. JOURNAL OF MATERIALS CHEMISTRY,2012,22(11):4811-4817.
APA Zhu, Zhao-Qi.,Sun, Han-Xue.,Qin, Xiao-Juan.,Jiang, Lei.,Pei, Chun-Juan.,...&Deng, Wei-Qiao.(2012).Preparation of poly(acrylic acid)-graphite oxide superabsorbent nanocomposites.JOURNAL OF MATERIALS CHEMISTRY,22(11),4811-4817.
MLA Zhu, Zhao-Qi,et al."Preparation of poly(acrylic acid)-graphite oxide superabsorbent nanocomposites".JOURNAL OF MATERIALS CHEMISTRY 22.11(2012):4811-4817.
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