Mesoporous carbons for supercapacitors obtained by the pyrolysis of block copolymers | |
Wang Yong1; Kong Ling-bin1,2; Li Xiao-ming1; Ran Fen1; Luo Yong-chun2; Kang Long2 | |
刊名 | NEW CARBON MATERIALS |
2015-08 | |
卷号 | 30期号:4页码:302-309 |
关键词 | Block copolymer Mesoporous carbon Polymer carbonization Energy storage Supercapacitor |
ISSN号 | 1007-8827 |
DOI | 10.1016/S1872-5805(15)60191-3 |
英文摘要 | Novel mesoporous carbons were prepared by the simple pyrolysis of block-copolymers, polyacrylonitrile-b-polystyreneb-polyacrylonitrile (PAN,b-PS-b-PAN), in which PAN generates a carbon network and PS is released to form mesopores after pyrolysis. The' block-copolymers were synthesized by reversible addition-fragmentation chain transfer (RAFT) polymerization and the molecular weight of each polymer block can be designed to tailor the porous structure of the mesoporous carbons. The carbons have high specific surface areas and a well-controlled mesopore size. The best mesoporous carbon has a high specific capacitance of 185 F.g(-1) at 0.625 A(.)g(-1) with a high power capability and a remarkable cycle stability in 2 mol/L KOH aqueous electrolyte. |
资助项目 | National Natural Science Foundation of China[51362018][21163010] ; Key Project of Chinese Ministry of Education[212183] |
WOS研究方向 | Materials Science |
语种 | 英语 |
出版者 | ELSEVIER SCIENCE BV |
WOS记录号 | WOS:000361585300003 |
状态 | 已发表 |
内容类型 | 期刊论文 |
源URL | [http://119.78.100.223/handle/2XXMBERH/34003] |
专题 | 材料科学与工程学院 设计艺术学院 |
通讯作者 | Kong Ling-bin |
作者单位 | 1.Lanzhou Univ Technol, Sch Mat Sci & Engn, State Key Lab Adv Proc & Recycling Nonferrous Met, Lanzhou 730050, Peoples R China 2.Lanzhou Univ Technol, Sch Mat Sci & Engn, Lanzhou 730050, Peoples R China |
推荐引用方式 GB/T 7714 | Wang Yong,Kong Ling-bin,Li Xiao-ming,et al. Mesoporous carbons for supercapacitors obtained by the pyrolysis of block copolymers[J]. NEW CARBON MATERIALS,2015,30(4):302-309. |
APA | Wang Yong,Kong Ling-bin,Li Xiao-ming,Ran Fen,Luo Yong-chun,&Kang Long.(2015).Mesoporous carbons for supercapacitors obtained by the pyrolysis of block copolymers.NEW CARBON MATERIALS,30(4),302-309. |
MLA | Wang Yong,et al."Mesoporous carbons for supercapacitors obtained by the pyrolysis of block copolymers".NEW CARBON MATERIALS 30.4(2015):302-309. |
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