Microporous carbon nanofibers prepared by combining electrospinning and phase separation methods for supercapacitor | |
Liu, Chang1; Tan, Yongtao1; Liu, Ying1; Shen, Kuiwen1; Peng, Bowu1; Niu, Xiaoqin1; Ran, Fen1,2 | |
刊名 | JOURNAL OF ENERGY CHEMISTRY |
2016-07 | |
卷号 | 25期号:4页码:587-593 |
关键词 | Supercapacitor Electrospinning Nanofiber Phase separation |
ISSN号 | 2095-4956 |
DOI | 10.1016/j.jechem.2016.03.017 |
英文摘要 | Microporous carbon nanofibers (MCNFs) derived from polyacrylonitrile nanofibers were fabricated via electrospinning technology and phase separation in the presence of polyvinylpyrrolidone (PVP). PVP together with a mixed solvent of N, N-Dimethylformamide and dimethyl sulfoxide was used as pore forming agent. The influences of PVP content in casting solution on the structure and electrochemical performance of the MCNFs were also investigated. The highest capacitance of 200 F/g was obtained on a three-electrode system at a scan rate of 0.5 A/g. The good performance was owing to the high specific surface area and the large amount of micro-pores, which enhanced the absorption and the transportation efficiency of electrolyte ion during charge/discharge process. This research indicated that the combination of electrospinning and phase separation technology could be used to fabricate microporous carbon nanofibers as electrode materials for supercapacitors with high specific surface area and outstanding electrochemical performance. (C) 2016 Science Press and Dalian Institute of Chemical Physics, Chinese Academy of Sciences. Published by Elsevier B.V. and Science Press. All rights reserved. |
资助项目 | National Natural Science Foundation of China[51203071][51363014][51362018] ; China Postdoctoral Science Foundation[2014M552509] ; Opening Project of State Key Laboratory of Polymer Materials Engineering (Sichuan University)[sklpme2014-4-25] ; Program for Hongliu Distinguished Young Scholars in Lanzhou University of Technology[J201402] ; University Scientific Research Project of Gansu Province[2014B-025] |
WOS研究方向 | Chemistry ; Energy & Fuels ; Engineering |
语种 | 英语 |
出版者 | ELSEVIER SCIENCE BV |
WOS记录号 | WOS:000388913300005 |
状态 | 已发表 |
内容类型 | 期刊论文 |
源URL | [http://119.78.100.223/handle/2XXMBERH/33654] |
专题 | 材料科学与工程学院 省部共建有色金属先进加工与再利用国家重点实验室 |
通讯作者 | Ran, Fen |
作者单位 | 1.Lanzhou Univ Technol, Sch Mat Sci & Engn, Lanzhou 730050, Gansu, Peoples R China 2.Lanzhou Univ Technol, State Key Lab Adv Proc & Recycling Nonferrous Met, Lanzhou 730050, Gansu, Peoples R China |
推荐引用方式 GB/T 7714 | Liu, Chang,Tan, Yongtao,Liu, Ying,et al. Microporous carbon nanofibers prepared by combining electrospinning and phase separation methods for supercapacitor[J]. JOURNAL OF ENERGY CHEMISTRY,2016,25(4):587-593. |
APA | Liu, Chang.,Tan, Yongtao.,Liu, Ying.,Shen, Kuiwen.,Peng, Bowu.,...&Ran, Fen.(2016).Microporous carbon nanofibers prepared by combining electrospinning and phase separation methods for supercapacitor.JOURNAL OF ENERGY CHEMISTRY,25(4),587-593. |
MLA | Liu, Chang,et al."Microporous carbon nanofibers prepared by combining electrospinning and phase separation methods for supercapacitor".JOURNAL OF ENERGY CHEMISTRY 25.4(2016):587-593. |
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