Synthesis and Properties of Conjugated Microporous Polymers Bearing Pyrazine Moieties with Macroscopically Porous 3D Networks Structures

doi:10.1002/mame.201600138

	Synthesis and Properties of Conjugated Microporous Polymers Bearing Pyrazine Moieties with Macroscopically Porous 3D Networks Structures
	Zang, Jiake 1; Zhu, Zhaoqi 1; Mu, Peng 1; Sun, Hanxue 1; Liang, Weidong 1; Yu, Fucheng 1; Chen, Lihua 2; Li, An 1
刊名	MACROMOLECULAR MATERIALS AND ENGINEERING
	2016-09
卷号	301 期号:9 页码:1104-1110
关键词	conjugated microporous polymers 3D networks metal ions adsorption capacity
ISSN号	1438-7492
DOI	10.1002/mame.201600138
英文摘要	The N-containing conjugated microporous polymers (CMPs) are synthesized by 2, 5-dibromopyrazine or its isomeric pyridazine monomer and 1,3,5-triethynylbenzene via the Pd(0)/Cu(I)-catalyzed Sonogashira-Hagihara cross-coupling polycondensation. The resulting CMPs exhibit diverse porosity and morphology, which reveals macroscopically porous 3D networks for BQCMP-1, agglomerated and amorphous structure for DQCMP-1, arising from the variation of isomeric mono mer. In addition, metal ions adsorption capacity of Zn(II), Cr(VI), Ni(II) have been investigated due to the good porosity of CMPs. Compared with Zn(II) and Cr(VI), the adsorption capacity of Ni(II) for BQCMP-1 and DQCMP-1 is maximal, which is 272 mg g(-1) and 559 mg g(-1). Our study may provide a useful guidance to manipulate CMPs by varying the constitution of isomeric monomer.
资助项目	Fund of Chinese Petroleum Changqing Oilfield Company[14AQ-FW-014]
WOS研究方向	Materials Science ; Polymer Science
语种	英语
出版者	WILEY-V C H VERLAG GMBH
WOS记录号	WOS:000383683500011
状态	已发表
内容类型	期刊论文
源URL	[http://119.78.100.223/handle/2XXMBERH/33614]
专题	材料科学与工程学院石油化工学院
通讯作者	Chen, Lihua; Li, An
作者单位	1.Lanzhou Univ Technol, Sch Mat Sci & Engn, Coll Petrochem Technol, Langongping Rd 287, Lanzhou 730050, Peoples R China 2.Northwest Univ Nationalities, Expt Ctr, Lanzhou 730030, Peoples R China
推荐引用方式 GB/T 7714	Zang, Jiake,Zhu, Zhaoqi,Mu, Peng,et al. Synthesis and Properties of Conjugated Microporous Polymers Bearing Pyrazine Moieties with Macroscopically Porous 3D Networks Structures[J]. MACROMOLECULAR MATERIALS AND ENGINEERING,2016,301(9):1104-1110.
APA	Zang, Jiake.,Zhu, Zhaoqi.,Mu, Peng.,Sun, Hanxue.,Liang, Weidong.,...&Li, An.(2016).Synthesis and Properties of Conjugated Microporous Polymers Bearing Pyrazine Moieties with Macroscopically Porous 3D Networks Structures.MACROMOLECULAR MATERIALS AND ENGINEERING,301(9),1104-1110.
MLA	Zang, Jiake,et al."Synthesis and Properties of Conjugated Microporous Polymers Bearing Pyrazine Moieties with Macroscopically Porous 3D Networks Structures".MACROMOLECULAR MATERIALS AND ENGINEERING 301.9(2016):1104-1110.