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High Volumetric Energy Density Capacitors Based on New Electrode Material Lanthanum Nitride
Zhang, Wei-Bin2; Ma, Xue-Jing2; Loh, Adeline1; Li, Xiaohong1; Walsh, Frank C.3; Kong, Ling-Bin2
刊名ACS ENERGY LETTERS
2017-02
卷号2期号:2页码:336-341
关键词Ammonia Capacitance Charge transfer Electrochemical electrodes Silver compounds Sodium sulfate
ISSN号2380-8195
DOI10.1021/acsenergylett.6b00636
英文摘要LaN is synthesized via calcining La2O3, in NH3 and studied as capacitive material for energy storage. A volumetric capacitance of 951.3 F cm(-3) was found in 1 mol dm(-3) Na2SO4 using a current density of 1 A g(-1), with less than 1% loss of capacitance being experienced after 5000 cycles. In addition, 87.3% of the initial capacitance remained at a current density of 10 A g(-1). LaN exhibits high capacitance that is attributed to subsurface space charge accumulation with a possible electric double-layer capacitor component. A reversible electrode process ensures long cycle life and favorable electrical charge transfer. The assembled LaN symmetrical capacitor showed high volumetric energy densities, facilitating high-duty applications.
WOS研究方向Chemistry ; Electrochemistry ; Energy & Fuels ; Science & Technology - Other Topics ; Materials Science
语种英语
出版者AMER CHEMICAL SOC
WOS记录号WOS:000394080000009
内容类型期刊论文
源URL[http://119.78.100.223/handle/2XXMBERH/33390]  
专题材料科学与工程学院
作者单位1.Univ Exeter, Coll Engn Math & Phys Sci, Renewable Energy Grp, Penryn Campus, Exeter TR10 9FE, Cornwall, England;
2.Lanzhou Univ Technol, Sch Mat Sci & Engn, State Key Lab Adv Proc & Recycling Nonferrous Met, Lanzhou 730050, Peoples R China;
3.Univ Southampton, Fac Engn & Environm, Energy Technol Grp, Electrochem Engn Lab, Southampton SO17 1BJ, Hants, England
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Zhang, Wei-Bin,Ma, Xue-Jing,Loh, Adeline,et al. High Volumetric Energy Density Capacitors Based on New Electrode Material Lanthanum Nitride[J]. ACS ENERGY LETTERS,2017,2(2):336-341.
APA Zhang, Wei-Bin,Ma, Xue-Jing,Loh, Adeline,Li, Xiaohong,Walsh, Frank C.,&Kong, Ling-Bin.(2017).High Volumetric Energy Density Capacitors Based on New Electrode Material Lanthanum Nitride.ACS ENERGY LETTERS,2(2),336-341.
MLA Zhang, Wei-Bin,et al."High Volumetric Energy Density Capacitors Based on New Electrode Material Lanthanum Nitride".ACS ENERGY LETTERS 2.2(2017):336-341.
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