Nitrogen-doped micro-nano carbon spheres with multi-scale pore structure obtained from interpenetrating polymer networks for electrochemical capacitors

doi:10.1039/c8ra05851b

CORC > 兰州理工大学 > 兰州理工大学 > 省部共建有色金属先进加工与再利用国家重点实验室

	Nitrogen-doped micro-nano carbon spheres with multi-scale pore structure obtained from interpenetrating polymer networks for electrochemical capacitors
	Hu, Bing 1; Zhang, Wei-Bin 1; Yan, Kun 1; Zhang, Tong 1; Li, Kai 1; Chen, Xi-Wen 1; Kang, Long 2; Kong, Ling-Bin 1,2
刊名	RSC ADVANCES
	2018
卷号	8 期号:61 页码:35083-35093
关键词	Carbon Carbonization Electrochemical electrodes Electrolytes Interpenetrating polymer networks Nitrogen Pore size Pore structure Potassium hydroxide Specific surface area Spheres
ISSN号	2046-2069
DOI	10.1039/c8ra05851b
英文摘要	A chemical process was developed to prepare N-doped micro-nano carbon spheres with multi-scale pore structures via carbonization of N-PF/PMMA interpenetrating polymer networks, which contain melamine resin as the nitrogen source, PF as the carbon source, and polymethylmethacrylate (PMMA) as the pore-former. The N-content of N-doped micro-nano carbon spheres was controlled by adjusting the mass ratio of melamine and phenol before polymerization. The N-doped micro-nano carbon spheres as electrode materials possess appropriate pore size distribution, higher specific surface area (559 m(2) g(-1)) and consistently dispersed nitrogen atoms with adjustable doping content. These distinct characteristics endow the prospective electrode materials with excellent performance in electrochemical capacitors. In particular, N-CS-IPN-4 exhibits the highest specific capacitance of 364 F g(-1) at 0.5 A g(-1) in 6 M KOH aqueous electrolyte in a three-electrode system. It also possesses superior rate capability (57.7% retention at current densities ranging from 0.5 to 50 A g(-1)) and excellent cycling performance at 2 A g(-1) (100% retention after 10000 cycles). All these results confirm that the N-doped micro-nano carbon spheres are promising electrochemical capacitor materials, which possesses the advantages of simple preparation procedure, multi-scale pore structures, higher specific surface areas, easy adjustment of N-content and excellent electrochemical properties.
资助项目	National Natural Science Foundation of China[51762031] ; Foundation for Innovation Groups of Basic Research in Gansu Province[1606RJIA322]
WOS研究方向	Chemistry
语种	英语
出版者	ROYAL SOC CHEMISTRY
WOS记录号	WOS:000448348600038
状态	已发表
内容类型	期刊论文
源URL	[http://119.78.100.223/handle/2XXMBERH/32854]
专题	省部共建有色金属先进加工与再利用国家重点实验室材料科学与工程学院石油化工学院
通讯作者	Kong, Ling-Bin
作者单位	1.Lanzhou Univ Technol, State Key Lab Adv Proc & Recycling Nonferrous Met, Lanzhou 730050, Gansu, Peoples R China 2.Lanzhou Univ Technol, Sch Mat Sci & Engn, Lanzhou 730050, Gansu, Peoples R China
推荐引用方式 GB/T 7714	Hu, Bing,Zhang, Wei-Bin,Yan, Kun,et al. Nitrogen-doped micro-nano carbon spheres with multi-scale pore structure obtained from interpenetrating polymer networks for electrochemical capacitors[J]. RSC ADVANCES,2018,8(61):35083-35093.
APA	Hu, Bing.,Zhang, Wei-Bin.,Yan, Kun.,Zhang, Tong.,Li, Kai.,...&Kong, Ling-Bin.(2018).Nitrogen-doped micro-nano carbon spheres with multi-scale pore structure obtained from interpenetrating polymer networks for electrochemical capacitors.RSC ADVANCES,8(61),35083-35093.
MLA	Hu, Bing,et al."Nitrogen-doped micro-nano carbon spheres with multi-scale pore structure obtained from interpenetrating polymer networks for electrochemical capacitors".RSC ADVANCES 8.61(2018):35083-35093.