Facile Preparation of Novel Hierarchically Porous Carbon at the Molecular Level for Supercapacitor Electrode Application | |
Li, Kai1; Zhang, Wei-Bin1; Zhao, Zhi-Yun1; Zhao, Yue1; Chen, Xi-Wen1; Kong, Ling-Bin1,2 | |
刊名 | NANO |
2018-08 | |
卷号 | 13期号:8 |
关键词 | Hierarchically porous carbon electrode material energy storage diblock copolymer atom transfer radical polymerization |
ISSN号 | 1793-2920 |
DOI | 10.1142/S1793292018500911 |
英文摘要 | Hierarchically porous carbons are obtained by a facile process of carbonizing the precursor of diblock copolymer xPS-b-polymethylmethacrylate (PMMA). In the diblock copolymer, there is a carbon source of cross-linked polystyrene (xPS) and a sacrificial block of PMMA. The atom transfer radical polymerization was used to synthesize the diblock copolymer with controlled molecular weight and narrow polydispersity in dimethylformamide at 120 degrees C. The obtained hierarchically porous carbons (HPCs) exhibit remarkable electrochemical properties, such as higher specific capacitance of 204 F g(-1) at the current density of 0.5 A g(-1) in 6 mol L-1 aqueous KOH electrolyte. In addition, it also presents an excellent rate performance of 64% capacitance retention as the current density increases to 10 A g(-1) and a superior cycling stability of 98% capacitance retention after 5000 cycles at the current density of 1 A g(-1). |
资助项目 | National Natural Science Foundation of China[51762031] ; Foundation for Innovation Groups of Basic Research in Gansu Province[1606RJIA322] |
WOS研究方向 | Science & Technology - Other Topics ; Materials Science ; Physics |
语种 | 英语 |
出版者 | WORLD SCIENTIFIC PUBL CO PTE LTD |
WOS记录号 | WOS:000443302800005 |
状态 | 已发表 |
内容类型 | 期刊论文 |
源URL | [http://119.78.100.223/handle/2XXMBERH/32511] |
专题 | 省部共建有色金属先进加工与再利用国家重点实验室 材料科学与工程学院 石油化工学院 |
通讯作者 | Kong, Ling-Bin |
作者单位 | 1.Lanzhou Univ Technol, State Key Lab Adv Proc & Recycling Nonferrous Met, Lanzhou 730050, Gansu, Peoples R China 2.Lanzhou Univ Technol, Sch Mat Sci & Engn, Lanzhou 730050, Gansu, Peoples R China |
推荐引用方式 GB/T 7714 | Li, Kai,Zhang, Wei-Bin,Zhao, Zhi-Yun,et al. Facile Preparation of Novel Hierarchically Porous Carbon at the Molecular Level for Supercapacitor Electrode Application[J]. NANO,2018,13(8). |
APA | Li, Kai,Zhang, Wei-Bin,Zhao, Zhi-Yun,Zhao, Yue,Chen, Xi-Wen,&Kong, Ling-Bin.(2018).Facile Preparation of Novel Hierarchically Porous Carbon at the Molecular Level for Supercapacitor Electrode Application.NANO,13(8). |
MLA | Li, Kai,et al."Facile Preparation of Novel Hierarchically Porous Carbon at the Molecular Level for Supercapacitor Electrode Application".NANO 13.8(2018). |
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