Facile Preparation of Novel Hierarchically Porous Carbon at the Molecular Level for Supercapacitor Electrode Application
Li, Kai1; Zhang, Wei-Bin1; Zhao, Zhi-Yun1; Zhao, Yue1; Chen, Xi-Wen1; Kong, Ling-Bin1,2
刊名NANO
2018-08
卷号13期号:8
关键词Hierarchically porous carbon electrode material energy storage diblock copolymer atom transfer radical polymerization
ISSN号1793-2920
DOI10.1142/S1793292018500911
英文摘要Hierarchically porous carbons are obtained by a facile process of carbonizing the precursor of diblock copolymer xPS-b-polymethylmethacrylate (PMMA). In the diblock copolymer, there is a carbon source of cross-linked polystyrene (xPS) and a sacrificial block of PMMA. The atom transfer radical polymerization was used to synthesize the diblock copolymer with controlled molecular weight and narrow polydispersity in dimethylformamide at 120 degrees C. The obtained hierarchically porous carbons (HPCs) exhibit remarkable electrochemical properties, such as higher specific capacitance of 204 F g(-1) at the current density of 0.5 A g(-1) in 6 mol L-1 aqueous KOH electrolyte. In addition, it also presents an excellent rate performance of 64% capacitance retention as the current density increases to 10 A g(-1) and a superior cycling stability of 98% capacitance retention after 5000 cycles at the current density of 1 A g(-1).
资助项目National Natural Science Foundation of China[51762031] ; Foundation for Innovation Groups of Basic Research in Gansu Province[1606RJIA322]
WOS研究方向Science & Technology - Other Topics ; Materials Science ; Physics
语种英语
出版者WORLD SCIENTIFIC PUBL CO PTE LTD
WOS记录号WOS:000443302800005
状态已发表
内容类型期刊论文
源URL[http://119.78.100.223/handle/2XXMBERH/32511]  
专题省部共建有色金属先进加工与再利用国家重点实验室
材料科学与工程学院
石油化工学院
通讯作者Kong, Ling-Bin
作者单位1.Lanzhou Univ Technol, State Key Lab Adv Proc & Recycling Nonferrous Met, Lanzhou 730050, Gansu, Peoples R China
2.Lanzhou Univ Technol, Sch Mat Sci & Engn, Lanzhou 730050, Gansu, Peoples R China
推荐引用方式
GB/T 7714
Li, Kai,Zhang, Wei-Bin,Zhao, Zhi-Yun,et al. Facile Preparation of Novel Hierarchically Porous Carbon at the Molecular Level for Supercapacitor Electrode Application[J]. NANO,2018,13(8).
APA Li, Kai,Zhang, Wei-Bin,Zhao, Zhi-Yun,Zhao, Yue,Chen, Xi-Wen,&Kong, Ling-Bin.(2018).Facile Preparation of Novel Hierarchically Porous Carbon at the Molecular Level for Supercapacitor Electrode Application.NANO,13(8).
MLA Li, Kai,et al."Facile Preparation of Novel Hierarchically Porous Carbon at the Molecular Level for Supercapacitor Electrode Application".NANO 13.8(2018).
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