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Novel Sugar Alcohol/Carbonized Kapok Fiber Composites as Form-Stable Phase-Change Materials with Exceptionally High Latent Heat for Thermal Energy Storage
An, Junru; Liang, Weidong; Mu, Peng; Wang, Chengjun; Chen, Tao; Zhu, Zhaoqi; Sun, Hanxue; Li, An
刊名ACS OMEGA
2019-03
卷号4期号:3页码:4848-4855
ISSN号2470-1343
DOI10.1021/acsomega.8b03373
英文摘要The development of form-stable phase-change materials (FSPCMs) with large latent heat, excellent thermal stability, and recyclability is essential for their practical applications in thermal or solar energy saving. In this paper, we first report the FSPCM composites with exceptional latent heat by employment of sugar alcohol, in this case erythritol (Ery) and mannitol (Man), as organic phase-change materials (PCMs) and carbonized kapok fiber (KKf) with a high Brunauer-Emmett-Teller surface area of up to 3396 m(2) g(-1) as porous supporting materials. The unique hollow tubelike structure of KKf makes it possible to load the organic PCMs inside and outside the KKf tubes, and a high load value of 93% was achieved. The carbonized KKf could not only endow itself robust thermal stability but also significantly decrease supercooling while enhancing the thermal conductivity of the PCM composites by over 130% compared with pure Ery and Man. Compared with these reported PCM composites for low and medium temperature usually having latent heat ranges from 150 to 258 J g(-1), our PCM composites display exceptionally high latent heat ranging from 297 to 350 J g(-1), owing to the inherent large latent heat of sugar alcohols. Notably, as a kind of natural plant fiber with abundant availability, the employment of kapok fiber as the supporting material via physical incorporation with sugar alcohols thus makes the approach simple, green, and cost-effective, which is of great technological significance for their real energy-saving applications owing to their high energy storage performance, high loading values, and enhanced thermal conductivity.
资助项目National Natural Science Foundation of China[51663012][51462021] ; Natural Science Foundation of Gansu Province, China[1610RJYA001] ; Innovation and Entrepreneurship Talent Project of Lanzhou[2017-RC-33]
WOS研究方向Chemistry
语种英语
出版者AMER CHEMICAL SOC
WOS记录号WOS:000462921900036
状态已发表
内容类型期刊论文
源URL[http://119.78.100.223/handle/2XXMBERH/32054]  
专题石油化工学院
材料科学与工程学院
发展规划处
通讯作者Liang, Weidong; Li, An
作者单位Lanzhou Univ Technol, Coll Petrochem Technol, Dept Chem Engn, Langongping Rd 287, Lanzhou 730050, Gansu, Peoples R China
推荐引用方式
GB/T 7714
An, Junru,Liang, Weidong,Mu, Peng,et al. Novel Sugar Alcohol/Carbonized Kapok Fiber Composites as Form-Stable Phase-Change Materials with Exceptionally High Latent Heat for Thermal Energy Storage[J]. ACS OMEGA,2019,4(3):4848-4855.
APA An, Junru.,Liang, Weidong.,Mu, Peng.,Wang, Chengjun.,Chen, Tao.,...&Li, An.(2019).Novel Sugar Alcohol/Carbonized Kapok Fiber Composites as Form-Stable Phase-Change Materials with Exceptionally High Latent Heat for Thermal Energy Storage.ACS OMEGA,4(3),4848-4855.
MLA An, Junru,et al."Novel Sugar Alcohol/Carbonized Kapok Fiber Composites as Form-Stable Phase-Change Materials with Exceptionally High Latent Heat for Thermal Energy Storage".ACS OMEGA 4.3(2019):4848-4855.
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