Effect of pH on the single-step synthesis of gold nanoparticles using PEO-PPO-PEO triblock copolymers in aqueous media | |
Shou, Qinghui; Guo, Chen; Yang, Liangrong; Jia, Lianwei; Liu, Chunzhao; Liu, Huizhou | |
刊名 | JOURNAL OF COLLOID AND INTERFACE SCIENCE
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2011-11-15 | |
卷号 | 363期号:2页码:481-489 |
关键词 | Gold Nanoparticles Pluronic Block copolymers pH value |
ISSN号 | 0021-9797 |
通讯作者 | Guo, C |
英文摘要 | The influence of pH value on gold nanoparticle production in the presence of Pluronic stabilizers is systematically investigated. The reactions are studied as a function of pH and at fixed concentrations of the two reactants, HAuCl(4) and P123 block copolymer. Results indicate that the reaction pathway during the nanoparticle formation can be controlled by varying pH. The nanoparticles synthesized at pH = 11.12 have an average diameter of 9.6 nm with a narrow size distribution, and the Pluronics are adsorbed on individual gold particle surfaces to form core-shell structures via hydrophobic interactions. The present work provides an economic way to improve the dispersion and stabilization of gold nanopartides and throws further light on the understanding of gold nanoparticle production using block copolymers. (C) 2011 Elsevier Inc. All rights reserved. |
WOS标题词 | Science & Technology ; Physical Sciences |
类目[WOS] | Chemistry, Physical |
研究领域[WOS] | Chemistry |
关键词[WOS] | OXIDE) BLOCK-COPOLYMERS ; METAL NANOPARTICLES ; AU NANOPARTICLES ; POLYMER MICELLES ; COLLOIDAL GOLD ; SIZE CONTROL ; PARTICLES ; STABILIZATION ; TEMPERATURE ; NANOCRYSTALS |
收录类别 | SCI |
语种 | 英语 |
WOS记录号 | WOS:000295192900008 |
公开日期 | 2013-10-30 |
内容类型 | 期刊论文 |
版本 | 出版稿 |
源URL | [http://ir.ipe.ac.cn/handle/122111/4580] ![]() |
专题 | 过程工程研究所_生化工程国家重点实验室 |
作者单位 | Chinese Acad Sci, Inst Proc Engn, State Key Lab Biochem Engn, Beijing 100190, Peoples R China |
推荐引用方式 GB/T 7714 | Shou, Qinghui,Guo, Chen,Yang, Liangrong,et al. Effect of pH on the single-step synthesis of gold nanoparticles using PEO-PPO-PEO triblock copolymers in aqueous media[J]. JOURNAL OF COLLOID AND INTERFACE SCIENCE,2011,363(2):481-489. |
APA | Shou, Qinghui,Guo, Chen,Yang, Liangrong,Jia, Lianwei,Liu, Chunzhao,&Liu, Huizhou.(2011).Effect of pH on the single-step synthesis of gold nanoparticles using PEO-PPO-PEO triblock copolymers in aqueous media.JOURNAL OF COLLOID AND INTERFACE SCIENCE,363(2),481-489. |
MLA | Shou, Qinghui,et al."Effect of pH on the single-step synthesis of gold nanoparticles using PEO-PPO-PEO triblock copolymers in aqueous media".JOURNAL OF COLLOID AND INTERFACE SCIENCE 363.2(2011):481-489. |
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