Synthesis, structure, and properties of Li2Pb2CuB4O10 with isolated [CuB4O10](6-) units

CORC > 新疆理化技术研究所 > 中国科学院新疆理化技术研究所 > 新疆维吾尔自治区电子信息材料与器件重点实验室

	Synthesis, structure, and properties of Li2Pb2CuB4O10 with isolated [CuB4O10](6-) units
	Li Hongyi; Pan Shilie; Wu Hongping; Smit Jared P.; Poeppelmeier Kenneth R.
刊名	JOURNAL OF ALLOYS AND COMPOUNDS
	2011
卷号	509 期号:7 页码:3310-3313
关键词	Oxide materials Solid state reactions Crystal structure X-ray diffraction
ISSN号	0925-8388
通讯作者	Pan, SL
中文摘要	The copper borate Li2Pb2CuB4O40 has been synthesized in air by the standard solid-state reaction at temperature in the range 550-650 degrees C and the structure of Li2Pb2CuB4O10 was determined by single-crystal X-ray diffraction. Li2Pb2CuB4O10 crystallizes in the monoclinic space group C2/c (no. 15) with a=16.8419(12), b=4.7895(4), c = 13.8976(10)angstrom, and beta = 125.3620(10)degrees, V=914.22(12)angstrom(3), and Z=4, as determined by single-crystal X-ray diffraction. The Li2Pb2CuB4O10 structure exhibits isolated units of stoichiometry CuB4O10(6-) that are built from CuO4 distorted square planes and triangular BO3 groups. The IR spectroscopy and thermal analysis investigations of Li2Pb2CuB4O10 are also presented. (C) 2010 Elsevier B.V. All rights reserved.
学科主题	Chemistry ; Materials Science ; Metallurgy & Metallurgical Engineering
收录类别	SCI
资助信息	National Natural Science Foundation of China 50802110; Chinese Academy of Sciences; "Western Light Joint Scholar Foundation" of Chinese Academy of Sciences; Scientific Research Foundation for the Returned Overseas Chinese Scholars, State Education Ministry 20091001; Natural Science Foundation of Xinjiang Uygur Autonomous Region of China 200821159, 2009211B33; "High Technology Research and Development Program" of Xinjiang Uygur Autonomous Region of China 200816120; National Science Foundation DMR-0604454
公开日期	2013-11-07
内容类型	期刊论文
源URL	[http://ir.xjipc.cas.cn/handle/365002/2796]
专题	新疆理化技术研究所_新疆维吾尔自治区电子信息材料与器件重点实验室
作者单位	Chinese Acad Sci, Xinjiang Tech Inst Phys & Chem, Xinjiang Key Lab Elect Informat Mat & Devices, Urumqi 830011, Peoples R China;Chinese Acad Sci, Grad Sch, Beijing 100039, Peoples R China;Northwestern Univ, Dept Chem, Evanston, IL 60208 USA
推荐引用方式 GB/T 7714	Li Hongyi,Pan Shilie,Wu Hongping,et al. Synthesis, structure, and properties of Li2Pb2CuB4O10 with isolated [CuB4O10](6-) units[J]. JOURNAL OF ALLOYS AND COMPOUNDS,2011,509(7):3310-3313.
APA	Li Hongyi,Pan Shilie,Wu Hongping,Smit Jared P.,&Poeppelmeier Kenneth R..(2011).Synthesis, structure, and properties of Li2Pb2CuB4O10 with isolated [CuB4O10](6-) units.JOURNAL OF ALLOYS AND COMPOUNDS,509(7),3310-3313.
MLA	Li Hongyi,et al."Synthesis, structure, and properties of Li2Pb2CuB4O10 with isolated [CuB4O10](6-) units".JOURNAL OF ALLOYS AND COMPOUNDS 509.7(2011):3310-3313.