Synthesis, structure, and properties of Li2Pb2CuB4O10 with isolated [CuB4O10](6-) units | |
Li Hongyi; Pan Shilie![]() | |
刊名 | JOURNAL OF ALLOYS AND COMPOUNDS
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2011 | |
卷号 | 509期号:7页码:3310-3313 |
关键词 | Oxide materials Solid state reactions Crystal structure X-ray diffraction |
ISSN号 | 0925-8388 |
通讯作者 | Pan, SL |
中文摘要 | The copper borate Li2Pb2CuB4O40 has been synthesized in air by the standard solid-state reaction at temperature in the range 550-650 degrees C and the structure of Li2Pb2CuB4O10 was determined by single-crystal X-ray diffraction. Li2Pb2CuB4O10 crystallizes in the monoclinic space group C2/c (no. 15) with a=16.8419(12), b=4.7895(4), c = 13.8976(10)angstrom, and beta = 125.3620(10)degrees, V=914.22(12)angstrom(3), and Z=4, as determined by single-crystal X-ray diffraction. The Li2Pb2CuB4O10 structure exhibits isolated units of stoichiometry CuB4O10(6-) that are built from CuO4 distorted square planes and triangular BO3 groups. The IR spectroscopy and thermal analysis investigations of Li2Pb2CuB4O10 are also presented. (C) 2010 Elsevier B.V. All rights reserved. |
学科主题 | Chemistry ; Materials Science ; Metallurgy & Metallurgical Engineering |
收录类别 | SCI |
资助信息 | National Natural Science Foundation of China 50802110; Chinese Academy of Sciences; "Western Light Joint Scholar Foundation" of Chinese Academy of Sciences; Scientific Research Foundation for the Returned Overseas Chinese Scholars, State Education Ministry 20091001; Natural Science Foundation of Xinjiang Uygur Autonomous Region of China 200821159, 2009211B33; "High Technology Research and Development Program" of Xinjiang Uygur Autonomous Region of China 200816120; National Science Foundation DMR-0604454 |
公开日期 | 2013-11-07 |
内容类型 | 期刊论文 |
源URL | [http://ir.xjipc.cas.cn/handle/365002/2796] ![]() |
专题 | 新疆理化技术研究所_新疆维吾尔自治区电子信息材料与器件重点实验室 |
作者单位 | Chinese Acad Sci, Xinjiang Tech Inst Phys & Chem, Xinjiang Key Lab Elect Informat Mat & Devices, Urumqi 830011, Peoples R China;Chinese Acad Sci, Grad Sch, Beijing 100039, Peoples R China;Northwestern Univ, Dept Chem, Evanston, IL 60208 USA |
推荐引用方式 GB/T 7714 | Li Hongyi,Pan Shilie,Wu Hongping,et al. Synthesis, structure, and properties of Li2Pb2CuB4O10 with isolated [CuB4O10](6-) units[J]. JOURNAL OF ALLOYS AND COMPOUNDS,2011,509(7):3310-3313. |
APA | Li Hongyi,Pan Shilie,Wu Hongping,Smit Jared P.,&Poeppelmeier Kenneth R..(2011).Synthesis, structure, and properties of Li2Pb2CuB4O10 with isolated [CuB4O10](6-) units.JOURNAL OF ALLOYS AND COMPOUNDS,509(7),3310-3313. |
MLA | Li Hongyi,et al."Synthesis, structure, and properties of Li2Pb2CuB4O10 with isolated [CuB4O10](6-) units".JOURNAL OF ALLOYS AND COMPOUNDS 509.7(2011):3310-3313. |
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