Effects of Alkali Halide Salts on Hydrocarboxylation of Styrene Catalyzed by Water-Soluble Palladium Phosphine Complexes

CORC > 新疆理化技术研究所 > 中国科学院新疆理化技术研究所 > 新疆维吾尔自治区精细化工工程技术研究中心

	Effects of Alkali Halide Salts on Hydrocarboxylation of Styrene Catalyzed by Water-Soluble Palladium Phosphine Complexes
	He Zhenhong; Hou Zhenshan; Luo Yanping; Zhou Liang; Liu Yuanfeng; Eli Wumanjiang
刊名	CATALYSIS LETTERS
	2013
卷号	143 期号:3 页码:289-297
关键词	Aqueous two-phase system Hydrocarboxylation Palladium-phosphine complexes Alkali metal halide
ISSN号	1011-372X
英文摘要	Hydrocarboxylation of styrene catalyzed by water-soluble Pd-TPPTS complexes was investigated. The reaction conditions, including reaction pressure, temperature, time and etc. have a significant influence on the catalytic performance. It was found that the yield of total acids and the selectivity towards 3-phenylpropionic acid were enhanced by adding a suitable amount of alkali metal halide salts. In addition, the reaction mechanism and the role of alkali metal halide salts in the reaction were discussed on the basis of the characterization of H-1 NMR and P-31 NMR.
学科主题	Chemistry
收录类别	SCI
WOS记录号	WOS:000315413700009
公开日期	2013-11-07
内容类型	期刊论文
源URL	[http://ir.xjipc.cas.cn/handle/365002/2674]
专题	新疆理化技术研究所_新疆维吾尔自治区精细化工工程技术研究中心
作者单位	Chinese Acad Sci, Xinjiang Tech Inst Phys & Chem, Urumqi 830011, Peoples R China;Chinese Acad Sci, Grad Univ, Beijing 100049, Peoples R China;E China Univ Sci & Technol, Key Lab Adv Mat, Res Inst Ind Catalysis, Shanghai 200237, Peoples R China
推荐引用方式 GB/T 7714	He Zhenhong,Hou Zhenshan,Luo Yanping,et al. Effects of Alkali Halide Salts on Hydrocarboxylation of Styrene Catalyzed by Water-Soluble Palladium Phosphine Complexes[J]. CATALYSIS LETTERS,2013,143(3):289-297.
APA	He Zhenhong,Hou Zhenshan,Luo Yanping,Zhou Liang,Liu Yuanfeng,&Eli Wumanjiang.(2013).Effects of Alkali Halide Salts on Hydrocarboxylation of Styrene Catalyzed by Water-Soluble Palladium Phosphine Complexes.CATALYSIS LETTERS,143(3),289-297.
MLA	He Zhenhong,et al."Effects of Alkali Halide Salts on Hydrocarboxylation of Styrene Catalyzed by Water-Soluble Palladium Phosphine Complexes".CATALYSIS LETTERS 143.3(2013):289-297.