Sr8ZnSc(PO4)(7):Eu3+Li+ novel red-emitting phosphors: Synthesis and photoluminescence properties | |
Gou, Jing1; Fana, Jingyan1; Luo, Meng1; Zuo, Shengnan1; Ye, Shufen1; Ma, Lingling1; Chen, Yali1; Wang, Mian1; Wang, Xuan2; Yu, Binxun1 | |
刊名 | MATERIALS RESEARCH BULLETIN
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2017-02 | |
卷号 | 86页码:234-240 |
关键词 | Phosphate Photoluminescence Phosphor |
ISSN号 | 0025-5408 |
DOI | 10.1016/j.materresbull.2016.10.021 |
英文摘要 | An effective strategy based on the host composition design has been adopted to obtain novel high luminescent efficiency red phosphor Sr7.6Zn1-xSc(PO4)(7):0.04Eu(3+),xLi(+). This research reveals that Li+ ions co-doping can offer charge compensation in host Sr8ZnSc(PO4)(7) with 5% mol Eu3+ doped and produce oxygen vacancies as the sensitizer transferring energy to nearby Eu3+. Meanwhile, Li+ ions can assist raising grain sizes of Sr7.6Zn1-xSc(PO4)(7):0.04Eu(3+),xLi(+) phosphors by lowering their melting temperature, further improve their luminescence koperties. The luminescence intensity of 595 and 618 nm emission bands of the optimal phosphor Sr7.6Zn0.97Sc(PO4)(7):0.04Eu(3+),0.03Li(+) achieved 2.932 and 3.316 times increase compared with the sample without Li+ ions incorporated, and it presented 1.26 times greater intensity than commercially red phosphor DS-200. Meanwhile, it also presented excellent thermal stability. Thus, the novel phosphors Sr7.6Zn1-xSc(PO4)(7):0.04Eu(3+),xLi(+) show the potential application value on WLEDs. (C) 2016 Elsevier Ltd. All rights reserved. |
资助项目 | National Natural Science Foundation of China[21603140] ; Fundamental Research Funds for the Central Universities[GK201603108][GK201603048] ; Natural Science Basic Research Plan in Shaanxi Province of China[2015JQ5140] ; Postgraduate Tutor Funds of the Education Department of Gansu Province[2013B-015] |
WOS研究方向 | Materials Science |
语种 | 英语 |
出版者 | PERGAMON-ELSEVIER SCIENCE LTD |
WOS记录号 | WOS:000390740200035 |
状态 | 已发表 |
内容类型 | 期刊论文 |
源URL | [http://119.78.100.223/handle/2XXMBERH/33384] ![]() |
专题 | 兰州理工大学 |
通讯作者 | Gou, Jing; Yu, Binxun |
作者单位 | 1.Shaanxi Normal Univ, Shaanxi Engn Lab Adv Energy Technol, Sch Mat Sci & Engn, Sch Chem & Chem Engn, Xian 710119, Peoples R China 2.Lanzhou Univ Technol, Sch Sci, Lanzhou 730050, Peoples R China |
推荐引用方式 GB/T 7714 | Gou, Jing,Fana, Jingyan,Luo, Meng,et al. Sr8ZnSc(PO4)(7):Eu3+Li+ novel red-emitting phosphors: Synthesis and photoluminescence properties[J]. MATERIALS RESEARCH BULLETIN,2017,86:234-240. |
APA | Gou, Jing.,Fana, Jingyan.,Luo, Meng.,Zuo, Shengnan.,Ye, Shufen.,...&Yu, Binxun.(2017).Sr8ZnSc(PO4)(7):Eu3+Li+ novel red-emitting phosphors: Synthesis and photoluminescence properties.MATERIALS RESEARCH BULLETIN,86,234-240. |
MLA | Gou, Jing,et al."Sr8ZnSc(PO4)(7):Eu3+Li+ novel red-emitting phosphors: Synthesis and photoluminescence properties".MATERIALS RESEARCH BULLETIN 86(2017):234-240. |
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