The influence of different Si : C ratios on the electrochemical performance of silicon/carbon layered film anodes for lithium-ion batteries | |
Wang, Jun1,2; Li, Shengli1; Zhao, Yi1; Shi, Juan1; Lv, Lili1; Wang, Huazhi1; Zhang, Zhiya1; Feng, Wangjun3 | |
刊名 | RSC ADVANCES
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2018 | |
卷号 | 8期号:12页码:6660-6666 |
ISSN号 | 2046-2069 |
DOI | 10.1039/c7ra12027c |
英文摘要 | With a high specific capacity (4200 mA h g(-1)), silicon based materials have become the most promising anode materials in lithium-ions batteries. However, the large volume expansion makes the capacity reduce rapidly. In this work, a periodic silicon/carbon (Si/C) multilayer thin film was synthesized by magnetron sputtering method on copper foil. The titanium(Ti) film (about 20 nm) as the transition layer was deposited on the copper foil prior to the deposition of the multilayer film. Superior electrochemical lithium storage performance was obtained by the multilayer thin film. The initial discharge and charge specific capacity of the Si (15 nm)/C (5 nm) multilayer film anode are 2640 mA h g(-1) and 2560 mA h g (-1) with an initial coulombic efficiency of similar to 97%. The retention specific capacity is about 2300 mA h g(-1) and there is similar to 87% capacity retention after 200 cycles. |
WOS研究方向 | Chemistry |
语种 | 英语 |
出版者 | ROYAL SOC CHEMISTRY |
WOS记录号 | WOS:000425034000056 |
内容类型 | 期刊论文 |
源URL | [http://119.78.100.223/handle/2XXMBERH/32946] ![]() |
专题 | 兰州理工大学 |
作者单位 | 1.Lanzhou Univ, Sch Phys Sci & Technol, Lanzhou 730000, Gansu, Peoples R China; 2.Chinese Acad Sci, State Key Lab Solid Lubricat, Lanzhou Inst Chem Phys, Lanzhou 730000, Gansu, Peoples R China 3.LanZhou Univ Technol, Sch Sci, Lanzhou 730000, Gansu, Peoples R China; |
推荐引用方式 GB/T 7714 | Wang, Jun,Li, Shengli,Zhao, Yi,et al. The influence of different Si : C ratios on the electrochemical performance of silicon/carbon layered film anodes for lithium-ion batteries[J]. RSC ADVANCES,2018,8(12):6660-6666. |
APA | Wang, Jun.,Li, Shengli.,Zhao, Yi.,Shi, Juan.,Lv, Lili.,...&Feng, Wangjun.(2018).The influence of different Si : C ratios on the electrochemical performance of silicon/carbon layered film anodes for lithium-ion batteries.RSC ADVANCES,8(12),6660-6666. |
MLA | Wang, Jun,et al."The influence of different Si : C ratios on the electrochemical performance of silicon/carbon layered film anodes for lithium-ion batteries".RSC ADVANCES 8.12(2018):6660-6666. |
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