Interlayer environment engineered MXene: Pre-intercalated Zn2+ ions as intercalants renders the modulated Li storage

doi:10.1016/j.jechem.2021.11.019

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	Interlayer environment engineered MXene: Pre-intercalated Zn2+ ions as intercalants renders the modulated Li storage
	Wang, Yixuan 2; Liu, Miao 2; Wang, Zhihe 2; Gu, Qinhua 1,3; Liu, Bo 4; Zhao, Cuimei 4; Zhang, Junkai 2; Xu, Shichong 2; Lu, Ming 2,3,4; Li, Haibo 2
刊名	JOURNAL OF ENERGY CHEMISTRY
	2022-05-01
卷号	68 页码:306-313
关键词	Ti (3) C (2) T- x MXene Zinc ions Interlayer intercalation Lithium storage
ISSN号	2095-4956
DOI	10.1016/j.jechem.2021.11.019
通讯作者	Lu, Ming(luming@jlnu.edu.cn) ; Li, Haibo(lihaibo@jlnu.edu.cn) ; Zhang, Bingsen(bszhang@imr.ac.cn)
英文摘要	The intercalation of foreign species into MXene, as an approach of tuning the interlayer environment, is employed to improve electrochemical ion storage behaviors. Herein, to understand the effect of confined ions by the MXene layers on the performance of electrochemical energy storage, Zn2+ ions were employed to intercalate into MXene via an electrochemical technique. Zn2+& nbsp;ions induced a shrink of the adjacent MXene layers. Meaningfully, a higher capacity of lithium ion storage was obtained after Zn2+& nbsp;pre intercalation. In order to explore the roles of the intercalated Zn2+& nbsp;ions, the structural evolution, and the electronic migration among Zn, Ti and the surface termination were investigated to trace the origination of the higher Li+ storage capacity. The pre-intercalated Zn2+& nbsp;ions lost electrons, meanwhile Ti of MXene obtained electrons. Moreover, a low-F surface functional groups was achieved. Contrary to the first shrink, after 200 cycles, a larger interlayer distance was monitored, this can accelerate the ion transport and offer a larger expansile space for lithium storage. This may offer a guidance to understand the roles of the confined ion by two-dimensional (2D) layered materials. (C)& nbsp;2021 Science Press and Dalian Institute of Chemical Physics, Chinese Academy of Sciences. Publishedby ELSEVIER B.V. and Science Press. All rights reserved.
资助项目	Development Plan of Science and Technology of Jilin Province[20190201309JC] ; Development Plan of Science and Technology of Jilin Province[YDZJ202101ZYTS187] ; Project of Development and Reform Commission of Jilin Provinve[2019C042-1] ; Science and Tech-nology Research Project of Education Department of Jilin Province[JJKH20210453KJ] ; Science and Tech-nology Research Project of Education Department of Jilin Province[JJKH20210449KJ] ; National Natural Science Foundation of China[51932005] ; Liaoning Revitalization Talents Program[XLYC1807175]
WOS研究方向	Chemistry ; Energy & Fuels ; Engineering
语种	英语
出版者	ELSEVIER
WOS记录号	WOS:000781371700006
资助机构	Development Plan of Science and Technology of Jilin Province ; Project of Development and Reform Commission of Jilin Provinve ; Science and Tech-nology Research Project of Education Department of Jilin Province ; National Natural Science Foundation of China ; Liaoning Revitalization Talents Program
内容类型	期刊论文
源URL	[http://ir.imr.ac.cn/handle/321006/172776]
专题	金属研究所_中国科学院金属研究所
通讯作者	Lu, Ming; Li, Haibo; Zhang, Bingsen
作者单位	1.Univ Sci & Techonol China, Sch Mat Sci & Engn, Shenyang 110016, Liaoning, Peoples R China 2.Jilin Normal Univ, Joint Lab MXene Mat, Key Lab Funct Mat Phys & Chem, Minist Educ, Changchun 130103, Jilin, Peoples R China 3.Chinese Acad Sci, Inst Met Res, Shenyang Natl Lab Mat Sci, Shenyang 110016, Liaoning, Peoples R China 4.Jilin Normal Univ, Key Lab Preparat & Applicat Environm Friendly Mat, Minist Educ, Changchun 130103, Jilin, Peoples R China
推荐引用方式 GB/T 7714	Wang, Yixuan,Liu, Miao,Wang, Zhihe,et al. Interlayer environment engineered MXene: Pre-intercalated Zn2+ ions as intercalants renders the modulated Li storage[J]. JOURNAL OF ENERGY CHEMISTRY,2022,68:306-313.
APA	Wang, Yixuan.,Liu, Miao.,Wang, Zhihe.,Gu, Qinhua.,Liu, Bo.,...&Zhang, Bingsen.(2022).Interlayer environment engineered MXene: Pre-intercalated Zn2+ ions as intercalants renders the modulated Li storage.JOURNAL OF ENERGY CHEMISTRY,68,306-313.
MLA	Wang, Yixuan,et al."Interlayer environment engineered MXene: Pre-intercalated Zn2+ ions as intercalants renders the modulated Li storage".JOURNAL OF ENERGY CHEMISTRY 68(2022):306-313.