Structural and compositional control in copper selenide nanocrystals for light-induced self-repairable electrodes | |
Singh, S. C.; Li, H. Y.; Yao, C. N.; Zhan, Z.; Yu, W. L.; Yu, Z.; Guo, C. L. | |
刊名 | Nano Energy
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2018 | |
卷号 | 51页码:774-785 |
关键词 | Copper selenide Self-repairable electrodes Localized surface plasmon resonance Compositional control Free charge carrier density Photo-electrochemical surface-plasmon resonances metal chalcogenides crystal-structure facile synthesis quantum dots batteries challenges cu2se Chemistry Science & Technology - Other Topics Materials Science Physics |
ISSN号 | 2211-2855 |
DOI | 10.1016/j.nanoen.2018.07.020 |
英文摘要 | In nature, self-healing can be induced by sunlight for damage and wound repair, and this phenomenon is very important to living species for prolonging their lives. This self-repairing feature is obviously highly desirable for non-biological materials and manmade systems. In this paper, we demonstrate, for the first time, that battery electrodes can be self-repaired when exposed to sunlight. Here, we show that the optical, and photoelectrochemical (PEC) properties can be controlled by varying structural and compositional parameters of copper selenide nanocrystals (NCs). Cation to anion ratio in copper selenide (Cu-2 (+/-) Se-x) NCs can be controlled over a wide range of 1.3-2.7 by simply changing the reaction temperature and impurity. Light-induced self-repairable behavior is demonstrated with electrochemical (EC) and PEC performances of electrodes made with stoichiometric copper selenide NCs. This nature-inspired, self-repairing behavior can be applied to batteries, super-capacitors, and photo-electrochemical fuel generators. |
内容类型 | 期刊论文 |
源URL | [http://ir.ciomp.ac.cn/handle/181722/61160] ![]() |
专题 | 中国科学院长春光学精密机械与物理研究所 |
推荐引用方式 GB/T 7714 | Singh, S. C.,Li, H. Y.,Yao, C. N.,et al. Structural and compositional control in copper selenide nanocrystals for light-induced self-repairable electrodes[J]. Nano Energy,2018,51:774-785. |
APA | Singh, S. C..,Li, H. Y..,Yao, C. N..,Zhan, Z..,Yu, W. L..,...&Guo, C. L..(2018).Structural and compositional control in copper selenide nanocrystals for light-induced self-repairable electrodes.Nano Energy,51,774-785. |
MLA | Singh, S. C.,et al."Structural and compositional control in copper selenide nanocrystals for light-induced self-repairable electrodes".Nano Energy 51(2018):774-785. |
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