Excess spectroscopy and its applications in the study of solution chemistry

doi:10.1515/pac-2020-0107

	Excess spectroscopy and its applications in the study of solution chemistry
	Zhang, Yaqin 2; Wu, Zhiwei 2; Wang, Yaqian 1; He, Hongyan 2; Yu, Zhiwu 1
刊名	PURE AND APPLIED CHEMISTRY
	2020-10-01
卷号	92 期号:10 页码:1611-1626
关键词	excess spectroscopy hydrogen bond ICSC-36 ionic liquid micro heterogeneity solution structure
ISSN号	0033-4545
DOI	10.1515/pac-2020-0107
英文摘要	Characterization of structural heterogeneity of liquid solutions and the pursuit of its nature have been challenging tasks to solution chemists. In the last decade, an emerging method called excess spectroscopy has found applications in this area. The method, combining the merits of molecular spectroscopy and excess thermodynamic functions, shows the ability to enhance the apparent resolution of spectra, provides abundant information concerning solution structures and intermolecular interactions. In this review, the thinking and mathematics of the method, as well as its developments, are presented first. Then, research progress related to the exploration of the method is thoroughly reviewed. The materials are classified into two parts, small-molecular solutions and ionic liquid solutions. Finally, potential challenges and the perspective for further development of the method are discussed.
资助项目	National Science Fund for Excellent Young Scholars[21922813] ; National Natural Science Foundation of China[21733011] ; National Natural Science Foundation of China[21834006] ; Youth Innovation Promotion Association of CAS[2017066]
WOS关键词	HYDROGEN-BONDING INTERACTIONS ; IONIC LIQUID ; BINARY-MIXTURES ; DIMETHYL-SULFOXIDE ; MOLECULAR-DYNAMICS ; ALIPHATIC-ALCOHOLS ; WATER ; MICROHETEROGENEITY ; ACETONITRILE ; SYSTEMS
WOS研究方向	Chemistry
语种	英语
出版者	WALTER DE GRUYTER GMBH
WOS记录号	WOS:000580659100008
资助机构	National Science Fund for Excellent Young Scholars ; National Natural Science Foundation of China ; Youth Innovation Promotion Association of CAS
内容类型	期刊论文
源URL	[http://ir.ipe.ac.cn/handle/122111/42454]
专题	中国科学院过程工程研究所
通讯作者	He, Hongyan; Yu, Zhiwu
作者单位	1.Tsinghua Univ, Dept Chem, MOE Key Lab Bioorgan Phosphorous Chem & Chem Biol, Beijing 100084, Peoples R China 2.Chinese Acad Sci, Inst Proc Engn, Beijing Key Lab Ion Liquids Clean Proc, CAS Key Lab Green Proc & Engn,State Key Lab Multi, Beijing 100190, Peoples R China
推荐引用方式 GB/T 7714	Zhang, Yaqin,Wu, Zhiwei,Wang, Yaqian,et al. Excess spectroscopy and its applications in the study of solution chemistry[J]. PURE AND APPLIED CHEMISTRY,2020,92(10):1611-1626.
APA	Zhang, Yaqin,Wu, Zhiwei,Wang, Yaqian,He, Hongyan,&Yu, Zhiwu.(2020).Excess spectroscopy and its applications in the study of solution chemistry.PURE AND APPLIED CHEMISTRY,92(10),1611-1626.
MLA	Zhang, Yaqin,et al."Excess spectroscopy and its applications in the study of solution chemistry".PURE AND APPLIED CHEMISTRY 92.10(2020):1611-1626.