Preparation of magnetic gamma-Al2O3 supported palladium catalyst for hydrogenation of nitrobenzene

CORC > 过程工程研究所 > 中国科学院过程工程研究所 > 研究所（批量导入）

	Preparation of magnetic gamma-Al2O3 supported palladium catalyst for hydrogenation of nitrobenzene
	Lang, Yuqi; Wang, Qiaoqiao; Xing, Jianmin; Zhang, Bo; Liu, Huizhou
刊名	AICHE JOURNAL
	2008-09-01
卷号	54 期号:9 页码:2303-2309
关键词	magnetic alumina nanoparticle superparamagnetic palladium
ISSN号	0001-1541
其他题名	Aiche J.
中文摘要	Spherical alumina support with magnetic core of 134 nm in diameter was prepared by the controlled hydrolysis of aluminums iso-propoxide. The magnetite Fe3O4 nanoparticles were first synthesized by coprecipitation. Later silica film was coated onto the surface of Fe3O4 nano particles with the sodium silicate acidification method. Alumina was supported on Fe3O4/SiO2 film by the controlled hydrolysis of aluminum alkoxide in a dilute solution consisting of cyclohexane and 2-propanol. Finally, magnetic alumina supported palladium catalysts were prepared by microemulsion method. The surface morphology and crystal structure of the magnetic alumina and catalysts were characterized by XRD, TEM, BET, and VSM, respectively. The results showed that these kinds of composite particle exhibit superparamagnetic behavior with zero coercivity and remanence. The catalysts show high activity for nitrobenzene directly hydrogenating to aniline under mild conditions. (C) 2008 American Institute of Chemical Engineers.
英文摘要	Spherical alumina support with magnetic core of 134 nm in diameter was prepared by the controlled hydrolysis of aluminums iso-propoxide. The magnetite Fe3O4 nanoparticles were first synthesized by coprecipitation. Later silica film was coated onto the surface of Fe3O4 nano particles with the sodium silicate acidification method. Alumina was supported on Fe3O4/SiO2 film by the controlled hydrolysis of aluminum alkoxide in a dilute solution consisting of cyclohexane and 2-propanol. Finally, magnetic alumina supported palladium catalysts were prepared by microemulsion method. The surface morphology and crystal structure of the magnetic alumina and catalysts were characterized by XRD, TEM, BET, and VSM, respectively. The results showed that these kinds of composite particle exhibit superparamagnetic behavior with zero coercivity and remanence. The catalysts show high activity for nitrobenzene directly hydrogenating to aniline under mild conditions. (C) 2008 American Institute of Chemical Engineers.
WOS标题词	Science & Technology ; Technology
类目[WOS]	Engineering, Chemical
研究领域[WOS]	Engineering
关键词[WOS]	PARTICLES ; POLYMERIZATION ; NANOSPHERES ; ADSORPTION ; PROTEIN
收录类别	SCI
原文出处	://WOS:000258584600008
语种	英语
WOS记录号	WOS:000258584600008
公开日期	2013-10-08
内容类型	期刊论文
版本	出版稿
源URL	[http://ir.ipe.ac.cn/handle/122111/2783]
专题	过程工程研究所_研究所（批量导入）
作者单位	Chinese Acad Sci, Inst Proc Engn, State Key Lab Biochem Engn, Lab Separat Sci & Engn, Beijing 100080, Peoples R China
推荐引用方式 GB/T 7714	Lang, Yuqi,Wang, Qiaoqiao,Xing, Jianmin,et al. Preparation of magnetic gamma-Al2O3 supported palladium catalyst for hydrogenation of nitrobenzene[J]. AICHE JOURNAL,2008,54(9):2303-2309.
APA	Lang, Yuqi,Wang, Qiaoqiao,Xing, Jianmin,Zhang, Bo,&Liu, Huizhou.(2008).Preparation of magnetic gamma-Al2O3 supported palladium catalyst for hydrogenation of nitrobenzene.AICHE JOURNAL,54(9),2303-2309.
MLA	Lang, Yuqi,et al."Preparation of magnetic gamma-Al2O3 supported palladium catalyst for hydrogenation of nitrobenzene".AICHE JOURNAL 54.9(2008):2303-2309.