Trimetallic yttrium N-(2-methylquinolin-8-yl)benzamides: synthesis, structure and use in ring-opening polymerization (ROP) of epsilon-caprolactone

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	Trimetallic yttrium N-(2-methylquinolin-8-yl)benzamides: synthesis, structure and use in ring-opening polymerization (ROP) of epsilon-caprolactone
	Zhang WJ(张文娟)1,2; Liu SF(刘绍峰)1,2; Sun WH(孙文华)1,2,3; Hao X(郝项)1,2; Carl Redshaw 4
刊名	New Journal of Chemistry
	2012
卷号	36 期号:11 页码:2392-2396
ISSN号	1144-0546
通讯作者	孙文华
英文摘要	A series of trimetallic yttrium complexes, L₇Y₃Cl₂ [L = N-(2-methylquinolin-8-yl)-p-R-benzamides, 1: R = H; 2: R = OMe; 3: R = Me; 4: R = Cl], has been synthesized by the stoichiometric reaction of YCl₃(THF)₂ with the corresponding potassium amidates. All complexes have been characterized by elemental analysis and NMR spectroscopy. The molecular structure of complex 1 bearing seven amidate ligands was confirmed by single-crystal X-ray diffraction. Screening of these complexes, in the presence of BnOH, for ring-opening polymerization of caprolactone (e-CL) revealed effective activities.
学科主题	物理化学
收录类别	SCI
资助信息	National Natural Science Foundation of China (No. 20904059). CR wishes to thank the EPSRC for an overseas travel grant (EP/H031855/1)
语种	英语
WOS记录号	WOS:000310721000036
公开日期	2013-10-11
内容类型	期刊论文
源URL	[http://210.77.64.217/handle/362003/3883]
专题	兰州化学物理研究所_OSSO国家重点实验室
作者单位	1.Chinese Acad Sci, Key Lab Engn Plast, Inst Chem, Beijing 100190, Peoples R China 2.Chinese Acad Sci, Beijing Natl Lab Mol Sci, Inst Chem, Beijing 100190, Peoples R China 3.Chinese Acad Sci, State Key Lab Oxo Synth & Select Oxidat, Lanzhou Inst Chem Phys, Lanzhou 730000, Peoples R China 4.Univ E Anglia, Sch Chem, Norwich NR4 7TJ, Norfolk, England
推荐引用方式 GB/T 7714	Zhang WJ,Liu SF,Sun WH,et al. Trimetallic yttrium N-(2-methylquinolin-8-yl)benzamides: synthesis, structure and use in ring-opening polymerization (ROP) of epsilon-caprolactone[J]. New Journal of Chemistry,2012,36(11):2392-2396.
APA	Zhang WJ,Liu SF,Sun WH,Hao X,&Carl Redshaw.(2012).Trimetallic yttrium N-(2-methylquinolin-8-yl)benzamides: synthesis, structure and use in ring-opening polymerization (ROP) of epsilon-caprolactone.New Journal of Chemistry,36(11),2392-2396.
MLA	Zhang WJ,et al."Trimetallic yttrium N-(2-methylquinolin-8-yl)benzamides: synthesis, structure and use in ring-opening polymerization (ROP) of epsilon-caprolactone".New Journal of Chemistry 36.11(2012):2392-2396.