Enantioselective oxidation of racemic secondary alcohols catalyzed by chiral Mn(III)-salen complexes with N-bromosuccinimide as a powerful oxidant

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	Enantioselective oxidation of racemic secondary alcohols catalyzed by chiral Mn(III)-salen complexes with N-bromosuccinimide as a powerful oxidant
	Xu DQ(徐大乾)1,2; Wang SF(王寿峰)1 ; Shen ZQ(沈志强)1 ; Xia CG(夏春谷)1 ; Sun W(孙伟)1
刊名	Organic and Biomolecular Chemistry
	2012
卷号	10 期号:14 页码:2730-2732
ISSN号	1477-0520
通讯作者	孙伟
英文摘要	We demonstrate an efficient enantioselective oxidation of secondary alcohols catalyzed by Mn(III)-salen complex using N-bromosuccinimide (NBS) as the oxidant. The new protocol is very efficient for the oxidative kinetic resolution of a variety of secondary alcohols, including ortho-substituted benzylic alcohols.
学科主题	物理化学与绿色催化
收录类别	SCI
资助信息	the Chinese Academy of Sciences;the National Natural Science Foundation of China (20873166;21073210;21133011)
语种	英语
WOS记录号	WOS:000301585600002
公开日期	2013-10-11
内容类型	期刊论文
源URL	[http://210.77.64.217/handle/362003/3855]
专题	兰州化学物理研究所_OSSO国家重点实验室
作者单位	1.Chinese Acad Sci, Lanzhou Inst Chem Phys, State Key Lab Oxo Synth & Select Oxidat, Lanzhou 730000, Peoples R China 2.Chinese Acad Sci, Grad Sch, Beijing, Peoples R China
推荐引用方式 GB/T 7714	Xu DQ,Wang SF,Shen ZQ,et al. Enantioselective oxidation of racemic secondary alcohols catalyzed by chiral Mn(III)-salen complexes with N-bromosuccinimide as a powerful oxidant[J]. Organic and Biomolecular Chemistry,2012,10(14):2730-2732.
APA	Xu DQ,Wang SF,Shen ZQ,Xia CG,&Sun W.(2012).Enantioselective oxidation of racemic secondary alcohols catalyzed by chiral Mn(III)-salen complexes with N-bromosuccinimide as a powerful oxidant.Organic and Biomolecular Chemistry,10(14),2730-2732.
MLA	Xu DQ,et al."Enantioselective oxidation of racemic secondary alcohols catalyzed by chiral Mn(III)-salen complexes with N-bromosuccinimide as a powerful oxidant".Organic and Biomolecular Chemistry 10.14(2012):2730-2732.