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Preparation and electrochemical properties of uniform spherical lithium rich materials xLi2MnO3 center dot(1-x)LiMn1/3Ni1/3Co1/3O2
Zhou, Sen1; Liu, Guoqiang1,2; Wen, Lei3; Luo, Hongze4
刊名JOURNAL OF ALLOYS AND COMPOUNDS
2021-09-05
卷号874页码:9
关键词Lithium ion batteries Li-rich material XLi2MnO3 (1-x)LiMn1 3Ni1 3Co1 Phase composition Electrochemical properties
ISSN号0925-8388
DOI10.1016/j.jallcom.2021.159885
通讯作者Liu, Guoqiang(liugq@smm.neu.edu.cn) ; Luo, Hongze(hongzee@gmail.com)
英文摘要The lithium-rich materials xLi2MnO3 & middot;(1-x)LiMn1/3Ni1/3Co1/3O2, with uniform spherical shape of 1 & micro;m are successfully prepared via a hydrothermal method combined with calcination process. The content of Li2MnO3 is tuned by adjusting the content of Li, which also affects their electrochemical performances. When the stoichiometry of Li is 1.05 (noted as Li 1.05), the obtained content of Li2MnO3 in the materials by XRD refinement is determined to be 59.94 wt%. It exhibits a relatively good electrochemical performance. At 1 C rate, the discharge capacity is 191.1 mAh g & minus;1, and the capacity retention rate is 83.9% after 100 cycles. (c) 2021 Elsevier B.V. All rights reserved.
资助项目National Natural Science Foundation of China[51574081]
WOS研究方向Chemistry ; Materials Science ; Metallurgy & Metallurgical Engineering
语种英语
出版者ELSEVIER SCIENCE SA
WOS记录号WOS:000653089500004
资助机构National Natural Science Foundation of China
内容类型期刊论文
源URL[http://ir.imr.ac.cn/handle/321006/161403]  
专题金属研究所_中国科学院金属研究所
通讯作者Liu, Guoqiang; Luo, Hongze
作者单位1.Northeastern Univ, Sch Met, Key Lab Ecol Met Multimetall Mineral, Minist Educ, Shenyang 110819, Peoples R China
2.Nankai Univ, Coll Chem, Key Lab Adv Energy Mat Chem, Minist Educ, Tianjin 300071, Peoples R China
3.Chinese Acad Sci, Inst Met Res, Shenyang 110016, Peoples R China
4.CSIR, Pretoria, South Africa
推荐引用方式
GB/T 7714
Zhou, Sen,Liu, Guoqiang,Wen, Lei,et al. Preparation and electrochemical properties of uniform spherical lithium rich materials xLi2MnO3 center dot(1-x)LiMn1/3Ni1/3Co1/3O2[J]. JOURNAL OF ALLOYS AND COMPOUNDS,2021,874:9.
APA Zhou, Sen,Liu, Guoqiang,Wen, Lei,&Luo, Hongze.(2021).Preparation and electrochemical properties of uniform spherical lithium rich materials xLi2MnO3 center dot(1-x)LiMn1/3Ni1/3Co1/3O2.JOURNAL OF ALLOYS AND COMPOUNDS,874,9.
MLA Zhou, Sen,et al."Preparation and electrochemical properties of uniform spherical lithium rich materials xLi2MnO3 center dot(1-x)LiMn1/3Ni1/3Co1/3O2".JOURNAL OF ALLOYS AND COMPOUNDS 874(2021):9.
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