Preparation of thermal stable supported metal (Cu, Au, Pd) nanoparticles via cross-linking cellulose gel confinement strategy | |
Peng, Weidan1,2; Yan, Yukun2; Zhang, Dawei1,2; Zhou, Yangtao2; Na, Duo2; Xiao, Chenjuan1,2; Yang, Chengling2; Wen, Guodong2; Zhang, Jinsong2 | |
刊名 | COLLOIDS AND SURFACES A-PHYSICOCHEMICAL AND ENGINEERING ASPECTS |
2021-09-05 | |
卷号 | 624页码:9 |
关键词 | Cellulose hydrogel Covalent cross-linking structure Metal nanoparticles Nitroaromatic hydrogenation |
ISSN号 | 0927-7757 |
DOI | 10.1016/j.colsurfa.2021.126809 |
通讯作者 | Zhang, Jinsong(jszhang@imr.ac.cn) |
英文摘要 | Hydrogel is low-cost porous material that has been used as effective support for confining metal nanoparticles due to its interconnected three-dimensional (3D) networks. Cellulose gel with covalently crosslinking has good thermal stability and can be used as support to stabilize metal nanoparticles in the high temperature environment. In this work, (Cu, Pd, Au) nanoparticles were immobilized on covalently crosslinked cellulose gel via adsorption and in situ reduction, followed by pyrolysis to obtain carbon-supported metal nanoparticles. Typically, the Cu nanoparticles were highly dispersed in the gels due to the interconnected networks and functional groups that restricted the aggregation of metal nanoparticles and improved the stability of the gel framework during pyrolysis. The results were confirmed by XRD, TEM, XPS, and FT-IR analyses. Furthermore, the Cu NPs exhibited good catalytic activity and selectivity for the hydrogenation of nitroaromatics with a TOF of 6656 h(-1), which was comparable to previously reported Pd catalysts. The catalyst remained its activity after 10 recycles, demonstrating the high stability and activity of the Cu NPs prepared by this method. This work provides a green synthetic pathway for the construction of size-controlled metal nanoparticles immobilized on a carbon support. |
资助项目 | Liaoning Revitalization Talents Program[XLYC1808013] ; SYNL[L2019F6] ; SYNL[L2019F15] |
WOS研究方向 | Chemistry |
语种 | 英语 |
出版者 | ELSEVIER |
WOS记录号 | WOS:000660291700005 |
资助机构 | Liaoning Revitalization Talents Program ; SYNL |
内容类型 | 期刊论文 |
源URL | [http://ir.imr.ac.cn/handle/321006/160609] |
专题 | 金属研究所_中国科学院金属研究所 |
通讯作者 | Zhang, Jinsong |
作者单位 | 1.Univ Sci & Technol China, Sch Mat Sci & Engn, Hefei 230026, Anhui, Peoples R China 2.Chinese Acad Sci, Inst Met Res, Shenyang Natl Lab Mat Sci, Shenyang 110016, Peoples R China |
推荐引用方式 GB/T 7714 | Peng, Weidan,Yan, Yukun,Zhang, Dawei,et al. Preparation of thermal stable supported metal (Cu, Au, Pd) nanoparticles via cross-linking cellulose gel confinement strategy[J]. COLLOIDS AND SURFACES A-PHYSICOCHEMICAL AND ENGINEERING ASPECTS,2021,624:9. |
APA | Peng, Weidan.,Yan, Yukun.,Zhang, Dawei.,Zhou, Yangtao.,Na, Duo.,...&Zhang, Jinsong.(2021).Preparation of thermal stable supported metal (Cu, Au, Pd) nanoparticles via cross-linking cellulose gel confinement strategy.COLLOIDS AND SURFACES A-PHYSICOCHEMICAL AND ENGINEERING ASPECTS,624,9. |
MLA | Peng, Weidan,et al."Preparation of thermal stable supported metal (Cu, Au, Pd) nanoparticles via cross-linking cellulose gel confinement strategy".COLLOIDS AND SURFACES A-PHYSICOCHEMICAL AND ENGINEERING ASPECTS 624(2021):9. |
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