Chiral Phosphine-Phosphoramidite Ligands for Highly Efficient Ir-Catalyzed Asymmetric Hydrogenation of Sterically Hindered N-Arylimines | |
Hou, Chuan-Jin1,2; Wang, Ya-Hui1; Zheng, Zhuo1; Xu, Jie1; Hu, Xiang-Ping1 | |
刊名 | organic letters
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2012-07-06 | |
卷号 | 14期号:13页码:3554-3557 |
通讯作者 | 胡向平 |
产权排序 | 1,1 |
英文摘要 | a mild and general iridium-catalyzed, highly enantioselective hydrogenation of sterically hindered n-arylimines with a new h-8-binol-derived phosphine-phosphoramidite ligand has been developed. the present catalytic system features high turnover numbers (up to 100000) and good to perfect enantioselectivities (up to 99% ee) for the hydrogenation of a variety of sterically hindered n-arylimines. |
学科主题 | 物理化学 |
WOS标题词 | science & technology ; physical sciences |
类目[WOS] | chemistry, organic |
研究领域[WOS] | chemistry |
关键词[WOS] | enantioselective hydrogenation ; imines ; hydroformylation ; complexes ; quinaphos ; derivatives |
收录类别 | SCI ; IC ; CCR |
语种 | 英语 |
WOS记录号 | WOS:000306050300081 |
公开日期 | 2013-10-11 |
内容类型 | 期刊论文 |
源URL | [http://159.226.238.44/handle/321008/118313] ![]() |
专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
作者单位 | 1.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian 116023, Peoples R China 2.Dalian Polytech Univ, Sch Light Ind & Chem Engn, Dalian 116034, Peoples R China |
推荐引用方式 GB/T 7714 | Hou, Chuan-Jin,Wang, Ya-Hui,Zheng, Zhuo,et al. Chiral Phosphine-Phosphoramidite Ligands for Highly Efficient Ir-Catalyzed Asymmetric Hydrogenation of Sterically Hindered N-Arylimines[J]. organic letters,2012,14(13):3554-3557. |
APA | Hou, Chuan-Jin,Wang, Ya-Hui,Zheng, Zhuo,Xu, Jie,&Hu, Xiang-Ping.(2012).Chiral Phosphine-Phosphoramidite Ligands for Highly Efficient Ir-Catalyzed Asymmetric Hydrogenation of Sterically Hindered N-Arylimines.organic letters,14(13),3554-3557. |
MLA | Hou, Chuan-Jin,et al."Chiral Phosphine-Phosphoramidite Ligands for Highly Efficient Ir-Catalyzed Asymmetric Hydrogenation of Sterically Hindered N-Arylimines".organic letters 14.13(2012):3554-3557. |
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