Chiral Phosphine-Phosphoramidite Ligands for Highly Efficient Ir-Catalyzed Asymmetric Hydrogenation of Sterically Hindered N-Arylimines

	Chiral Phosphine-Phosphoramidite Ligands for Highly Efficient Ir-Catalyzed Asymmetric Hydrogenation of Sterically Hindered N-Arylimines
	Hou, Chuan-Jin 1,2; Wang, Ya-Hui 1; Zheng, Zhuo 1; Xu, Jie 1; Hu, Xiang-Ping 1
刊名	organic letters
	2012-07-06
卷号	14 期号:13 页码:3554-3557
通讯作者	胡向平
产权排序	1,1
英文摘要	a mild and general iridium-catalyzed, highly enantioselective hydrogenation of sterically hindered n-arylimines with a new h-8-binol-derived phosphine-phosphoramidite ligand has been developed. the present catalytic system features high turnover numbers (up to 100000) and good to perfect enantioselectivities (up to 99% ee) for the hydrogenation of a variety of sterically hindered n-arylimines.
学科主题	物理化学
WOS标题词	science & technology ; physical sciences
类目[WOS]	chemistry, organic
研究领域[WOS]	chemistry
关键词[WOS]	enantioselective hydrogenation ; imines ; hydroformylation ; complexes ; quinaphos ; derivatives
收录类别	SCI ; IC ; CCR
语种	英语
WOS记录号	WOS:000306050300081
公开日期	2013-10-11
内容类型	期刊论文
源URL	[http://159.226.238.44/handle/321008/118313]
专题	大连化学物理研究所_中国科学院大连化学物理研究所
作者单位	1.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian 116023, Peoples R China 2.Dalian Polytech Univ, Sch Light Ind & Chem Engn, Dalian 116034, Peoples R China
推荐引用方式 GB/T 7714	Hou, Chuan-Jin,Wang, Ya-Hui,Zheng, Zhuo,et al. Chiral Phosphine-Phosphoramidite Ligands for Highly Efficient Ir-Catalyzed Asymmetric Hydrogenation of Sterically Hindered N-Arylimines[J]. organic letters,2012,14(13):3554-3557.
APA	Hou, Chuan-Jin,Wang, Ya-Hui,Zheng, Zhuo,Xu, Jie,&Hu, Xiang-Ping.(2012).Chiral Phosphine-Phosphoramidite Ligands for Highly Efficient Ir-Catalyzed Asymmetric Hydrogenation of Sterically Hindered N-Arylimines.organic letters,14(13),3554-3557.
MLA	Hou, Chuan-Jin,et al."Chiral Phosphine-Phosphoramidite Ligands for Highly Efficient Ir-Catalyzed Asymmetric Hydrogenation of Sterically Hindered N-Arylimines".organic letters 14.13(2012):3554-3557.