Synthesis of High-Quality Diesel with Furfural and 2-Methylfuran from Hemicellulose | |
Li, Guangyi1,2; Li, Ning1; Wang, Zhiqiang1,3; Li, Changzhi1; Wang, Aiqin1; Wang, Xiaodong1; Cong, Yu1; Zhang, Tao1 | |
刊名 | chemsuschem |
2012 | |
卷号 | 5期号:10页码:1958-1966 |
关键词 | renewable resources zirconium heterogeneous catalysis platinum biomass |
通讯作者 | 张涛 |
产权排序 | 1,1 |
英文摘要 | hydroxyalkylationalkylation (haa) coupled with hydrodeoxygenation is a promising route for the synthesis of renewable high-quality diesel or jet fuel. in this work, a series of solid-acid catalysts were firstly used for haa between lignocellulose-derived furan and carbonyl compounds. among the investigated catalysts, nafion-212 resin demonstrated the highest activity and stability. owing to the high activity of the reactants and the advantage in industrial integration, the haa of 2-methylfuran (2-mf) and furfural can be considered as a prospective route in future applications. catalyst loading, reaction temperature, and time had evident effects on the haa of 2-mf and furfural over nafion-212 resin. finally, the haa product of 2-mf and furfural was hydrogenated over a pd/c catalyst and hydrodeoxygenated over pt-loaded solid-acid catalysts. pt/zirconium phosphate (pt/zrp) was found to be the best catalyst for hydrodeoxygenation. over the 4?% pt/zrp catalyst, a 94?% carbon yield of diesel and 75?% carbon yield of c15 hydrocarbons (with 6-butylundecane as the major component) was achieved. |
学科主题 | 物理化学 |
类目[WOS] | chemistry, multidisciplinary |
研究领域[WOS] | chemistry |
关键词[WOS] | mesoporous sba-15 silica ; high-surface-area ; catalytic conversion ; aldol-condensation ; liquid fuels ; oxygenated hydrocarbons ; transportation fuels ; gamma-valerolactone ; ethylene-glycol ; bond formation |
收录类别 | SCI |
语种 | 英语 |
WOS记录号 | WOS:000310074200012 |
公开日期 | 2013-10-11 |
内容类型 | 期刊论文 |
源URL | [http://159.226.238.44/handle/321008/118126] |
专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
作者单位 | 1.Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Catalysis, Dalian 116023, Peoples R China 2.Chinese Acad Sci, Grad Univ, Beijing 10049, Peoples R China 3.Sichuan Univ, Dept Chem Engn, Chengdu 610065, Peoples R China |
推荐引用方式 GB/T 7714 | Li, Guangyi,Li, Ning,Wang, Zhiqiang,et al. Synthesis of High-Quality Diesel with Furfural and 2-Methylfuran from Hemicellulose[J]. chemsuschem,2012,5(10):1958-1966. |
APA | Li, Guangyi.,Li, Ning.,Wang, Zhiqiang.,Li, Changzhi.,Wang, Aiqin.,...&Zhang, Tao.(2012).Synthesis of High-Quality Diesel with Furfural and 2-Methylfuran from Hemicellulose.chemsuschem,5(10),1958-1966. |
MLA | Li, Guangyi,et al."Synthesis of High-Quality Diesel with Furfural and 2-Methylfuran from Hemicellulose".chemsuschem 5.10(2012):1958-1966. |
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