Turning main-group element magnesium into a highly active electrocatalyst for oxygen reduction reaction

doi:10.1038/s41467-020-14565-w

CORC > 上海应用物理研究所 > 中国科学院上海应用物理研究所 > 中科院上海应用物理研究所2011-2017年

	Turning main-group element magnesium into a highly active electrocatalyst for oxygen reduction reaction
	Liu, S ; Li, ZD ; Wang, CL ; Tao, WW ; Huang, MX ; Zuo, M ; Yang, Y ; Yang, K ; Zhang, LJ ; Chen, S
刊名	NATURE COMMUNICATIONS
	2020
卷号	11 期号:1 页码:-
关键词	FUNCTIONALIZED GRAPHITIC MATERIALS TRANSITION-METALS ELECTRONIC-STRUCTURE RATIONAL DESIGN CATALYSTS ORIGIN CARBON IRON SPECTROSCOPY EVOLUTION
ISSN号	2041-1723
DOI	10.1038/s41467-020-14565-w
文献子类	期刊论文
英文摘要	It is known that the main-group metals and their related materials show poor catalytic activity due to a broadened single resonance derived from the interaction of valence orbitals of adsorbates with the broad sp-band of main-group metals. However, Mg cofactors existing in enzymes are extremely active in biochemical reactions. Our density function theory calculations reveal that the catalytic activity of the main-group metals (Mg, Al and Ca) in oxygen reduction reaction is severely hampered by the tight-bonding of active centers with hydroxyl group intermediate, while the Mg atom coordinated to two nitrogen atoms has the near-optimal adsorption strength with intermediate oxygen species by the rise of p-band center position compared to other coordination environments. We experimentally demonstrate that the atomically dispersed Mg cofactors incorporated within graphene framework exhibits a strikingly high half-wave potential of 910 mV in alkaline media, turning a s/p-band metal into a highly active electrocatalyst.
语种	英语
内容类型	期刊论文
源URL	[http://ir.sinap.ac.cn/handle/331007/33233]
专题	上海应用物理研究所_中科院上海应用物理研究所2011-2017年
作者单位	1.Univ Sci & Technol China, Dept Mat Sci & Engn, Hefei 230026, Peoples R China 2.Boston Univ, Dept Mech Engn, Boston, MA 02215 USA 3.Shanghai Inst Appl Phys, Shanghai Synchrotron Radiat Facil, Shanghai 201203, Peoples R China 4.Univ Sci & Technol China, Hefei Natl Lab Phys Sci Microscale, Hefei 230026, Peoples R China 5.Acad Sci, High Magnet Field Lab Chinese, Anhui Prov Key Lab Condensed Matter Phys Extreme, Hefei 230031, Peoples R China
推荐引用方式 GB/T 7714	Liu, S,Li, ZD,Wang, CL,et al. Turning main-group element magnesium into a highly active electrocatalyst for oxygen reduction reaction[J]. NATURE COMMUNICATIONS,2020,11(1):-.
APA	Liu, S.,Li, ZD.,Wang, CL.,Tao, WW.,Huang, MX.,...&Chen, QW.(2020).Turning main-group element magnesium into a highly active electrocatalyst for oxygen reduction reaction.NATURE COMMUNICATIONS,11(1),-.
MLA	Liu, S,et al."Turning main-group element magnesium into a highly active electrocatalyst for oxygen reduction reaction".NATURE COMMUNICATIONS 11.1(2020):-.