SPEEK and functionalized mesoporous MCM-41 mixed matrix membranes for CO2 separations
Khan, Asim Laeeq2; Klaysom, Chalida2; Gahlaut, Amit2; Li, Xianfeng1; Vankelecom, Ivo F. J.2
刊名journal of materials chemistry
2012
卷号22期号:37页码:20057-20064
通讯作者李先锋
产权排序2,4
英文摘要mixed matrix membranes (mmms) composed of sulfonated aromatic poly(ether ether ketone) (speek) and -so3 functionalized mesoporous mcm-41 were prepared by the solution casting method. a speek polymer with a fixed degree of sulfonation was used for membrane synthesis. co2 permeation data and sem images of the synthesized mmms suggest that the functionalized fillers adhered well to the polymer matrix. gas permeation tests indicated that the addition of functionalized mcm-41 to the polymer matrix increased both the gas permeability and selectivity. the highest selectivities obtained here for co2/n-2 and co2/ch4 were 40.46 and 22.86 (at a co2 permeability of 21.04 barrer), respectively. in order to initiate the evaluation of the practical commercial viability of these membranes, they were tested under different operating pressures and temperatures.
学科主题物理化学
WOS标题词science & technology ; physical sciences ; technology
类目[WOS]chemistry, physical ; materials science, multidisciplinary
研究领域[WOS]chemistry ; materials science
关键词[WOS]cross-linking modification ; ion-exchange membranes ; gas separation ; nanoparticles ; composites ; permeation ; copolymers ; co2/ch4 ; size
收录类别SCI
语种英语
WOS记录号WOS:000308099900090
公开日期2013-10-11
内容类型期刊论文
源URL[http://159.226.238.44/handle/321008/117790]  
专题大连化学物理研究所_中国科学院大连化学物理研究所
作者单位1.Chinese Acad Sci, Dalian Inst Chem Phys, Div Energy Storage, Dalian 116023, Peoples R China
2.Katholieke Univ Leuven, Fac Bioengn Sci, Ctr Surface Chem & Catalysis, B-3001 Louvain, Belgium
推荐引用方式
GB/T 7714
Khan, Asim Laeeq,Klaysom, Chalida,Gahlaut, Amit,et al. SPEEK and functionalized mesoporous MCM-41 mixed matrix membranes for CO2 separations[J]. journal of materials chemistry,2012,22(37):20057-20064.
APA Khan, Asim Laeeq,Klaysom, Chalida,Gahlaut, Amit,Li, Xianfeng,&Vankelecom, Ivo F. J..(2012).SPEEK and functionalized mesoporous MCM-41 mixed matrix membranes for CO2 separations.journal of materials chemistry,22(37),20057-20064.
MLA Khan, Asim Laeeq,et al."SPEEK and functionalized mesoporous MCM-41 mixed matrix membranes for CO2 separations".journal of materials chemistry 22.37(2012):20057-20064.
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