Nanocomposite based on graphene and intercalated covalent organic frameworks with hydrosulphonyl groups for electrochemical determination of heavy metal ions

doi:10.1007/s00604-021-04956-1

CORC > 烟台海岸带研究所 > 中国科学院烟台海岸带研究所 > 山东省海岸带环境工程技术研究中心

	Nanocomposite based on graphene and intercalated covalent organic frameworks with hydrosulphonyl groups for electrochemical determination of heavy metal ions
	Pan, Fei 1,2,3; Tong, Chunyi 4; Wang, Zhaoyang 3; Han, Haitao 1; Liu, Pei 5; Pan, Dawei 1; Zhu, Rilong 3
刊名	MICROCHIMICA ACTA
	2021-09-01
卷号	188 期号:9 页码:9
关键词	Nanocomposite Covalent organic frameworks Graphene Heavy metal Sea water analysis Electrochemical sensors
ISSN号	0026-3672
DOI	10.1007/s00604-021-04956-1
通讯作者	Pan, Dawei(dwpan@yic.ac.cn) ; Zhu, Rilong(zrlden@hnu.edu.cn)
英文摘要	An electrochemical sensor constructed by intercalated composites was developed for determination of heavy metal ions. The intercalated composites were composed of hydrosulphonyl functional covalent organic frameworks (COF-SH) and graphene (G). The presence of numerous adsorption sites, such as 18 sulfur atoms and 30 nitrogen atoms per big circle of COFs on COF-SH, was beneficial for the accumulation of heavy metals, while the graphene enhanced the electrical conductivity. The obtained sensor under the optimal conditions successfully detected the presence of heavy metal ions in coastal water samples at concentrations ranging from 1 to 1000 mu g L-1. The detection limits of Cd (II), Pb (II), Cu (II), and Hg (II) were 0.3, 0.2, 0.2, and 1.1 mu g L-1, respectively. Furthermore, the sensor still exhibited good stability after multiple uses less than 5%. When it is used in the analysis of actual samples, the recovery of standard addition is higher than 95%. In sum, the combination of hydrosulphonyl functional COFs with graphene looks very promising for the assembly of sensors with high sensitivity toward the determination of heavy metal ions for coastal environmental monitoring.
资助项目	Basic Research Fund for Central Universities[531118010314] ; Environmental Protection Science and Technology Project of Hunan Province[20190011] ; National Key R&D Program of China[2019YFD0901103] ; Strategic Priority Research Program of Chinese Academy of Sciences[XDB42000000] ; Key R&D Program of Hunan Province[2019SK2281]
WOS关键词	PLATFORM ; REMOVAL ; LEAD
WOS研究方向	Chemistry
语种	英语
WOS记录号	WOS:000684221400001
资助机构	Basic Research Fund for Central Universities ; Environmental Protection Science and Technology Project of Hunan Province ; National Key R&D Program of China ; Strategic Priority Research Program of Chinese Academy of Sciences ; Key R&D Program of Hunan Province
内容类型	期刊论文
源URL	[http://ir.yic.ac.cn/handle/133337/29627]
专题	烟台海岸带研究所_山东省海岸带环境工程技术研究中心
通讯作者	Pan, Dawei; Zhu, Rilong
作者单位	1.Chinese Acad Sci, Res Ctr Coastal Environm Engn Technol Shandong Pr, Yantai Inst Coastal Zone Res,Shandong Key Lab Coa, CAS Key Lab Coastal Environm Proc & Ecol Remediat, Chunhui Rd 17, Yantai 264003, Shandong, Peoples R China 2.Univ Chinese Acad Sci, Beijing 100049, Peoples R China 3.Hunan Univ, Coll Chem & Chem Engn, Adv Catalyt Engn Res Ctr, Minist Educ, Lushan Rd S, Changsha 410082, Hunan, Peoples R China 4.Hunan Univ, Coll Biol, Changsha 410082, Peoples R China 5.Hunan Ecol Environm Monitoring Ctr, State Environm Protect Key Lab Monitoring Heavy M, Changsha 410082, Peoples R China
推荐引用方式 GB/T 7714	Pan, Fei,Tong, Chunyi,Wang, Zhaoyang,et al. Nanocomposite based on graphene and intercalated covalent organic frameworks with hydrosulphonyl groups for electrochemical determination of heavy metal ions[J]. MICROCHIMICA ACTA,2021,188(9):9.
APA	Pan, Fei.,Tong, Chunyi.,Wang, Zhaoyang.,Han, Haitao.,Liu, Pei.,...&Zhu, Rilong.(2021).Nanocomposite based on graphene and intercalated covalent organic frameworks with hydrosulphonyl groups for electrochemical determination of heavy metal ions.MICROCHIMICA ACTA,188(9),9.
MLA	Pan, Fei,et al."Nanocomposite based on graphene and intercalated covalent organic frameworks with hydrosulphonyl groups for electrochemical determination of heavy metal ions".MICROCHIMICA ACTA 188.9(2021):9.