Boron doped magnetic catalysts for selective transfer hydrogenation of furfural into furfuryl alcohol

doi:10.1016/j.ces.2020.116075

	Boron doped magnetic catalysts for selective transfer hydrogenation of furfural into furfuryl alcohol
	Li, Danni 1,2,4,5; Zhang, Jun 1,2,3,4; Liu, Ying 5; Yuan, Haoran 1,2,3,4; Chen, Yong 1,2,3,4
刊名	CHEMICAL ENGINEERING SCIENCE
	2021-01-16
卷号	229 页码:12
关键词	Magnetic catalysts Transfer hydrogenation Furfural Furfuryl alcohol Activation energy
ISSN号	0009-2509
DOI	10.1016/j.ces.2020.116075
通讯作者	Liu, Ying(amyliu@scut.edu.cn) ; Yuan, Haoran(yuanhr@ms.giec.ac.cn)
英文摘要	A series of boron doped magnetic zirconium catalysts were developed for the selective transfer hydrogenation of biomass-derived furfural (FFR) into furfuryl alcohol (FA) using 2-propanol as hydrogen source and solvent. Full characterizations with XRD, SEM, TG, Py-IR, NH3-TPD, and CO2-TPD techniques were undertaken to uncover structural properties of magnetic catalysts. Boron doped magnetic zirconium catalysts endowing with adjustable acid-base sites exhibited excellent performance as well as good regenerability in the transfer hydrogenation of FFR, where almost 100% FA yield was achieved in the presence of 2-propanol and the catalyst still sustained good activity after being used five times. Suitable acidity/ basicity ratio of 3.8 similar to 4.0 apparently benefited the selective production of FA. Gratifyingly, the activation energy for FA formation over Zr1B3FeO was as low as 48.3 kJ/mol. In addition, plausible reaction mechanism involving two H-transfer paths for transfer hydrogenation of FFR into FA under the catalysis of active Zr/B species was proposed. (c) 2020 Elsevier Ltd. All rights reserved.
资助项目	National Key R&D Program of China[2018YFC1901200] ; National Natural Science Foundation of China[51976222] ; Key Special Project for Introduced Talents Team of Southern Marine Science and Engineering Guangdong Laboratory (Guangzhou)[GML2019ZD0101] ; Natural Science Foundation of Guangdong Province, China[2018A030313856]
WOS关键词	PONNDORF-VERLEY REDUCTION ; EFFICIENT SYNTHESIS ; BIOMASS ; ACID ; CONVERSION ; ZIRCONIA ; COPPER ; VALEROLACTONE ; NANOPARTICLES ; MECHANISM
WOS研究方向	Engineering
语种	英语
出版者	PERGAMON-ELSEVIER SCIENCE LTD
WOS记录号	WOS:000583263000008
资助机构	National Key R&D Program of China ; National Natural Science Foundation of China ; Key Special Project for Introduced Talents Team of Southern Marine Science and Engineering Guangdong Laboratory (Guangzhou) ; Natural Science Foundation of Guangdong Province, China
内容类型	期刊论文
源URL	[http://ir.giec.ac.cn/handle/344007/34859]
专题	中国科学院广州能源研究所
通讯作者	Liu, Ying; Yuan, Haoran
作者单位	1.Guangdong Prov Key Lab New & Renewable Energy Res, Guangzhou 510640, Peoples R China 2.CAS Key Lab Renewable Energy, Guangzhou 510640, Peoples R China 3.Southern Marine Sci & Engn Guangdong Lab, Guangzhou 511458, Peoples R China 4.Chinese Acad Sci, Guangzhou Inst Energy Convers, Guangzhou 510640, Peoples R China 5.South China Univ Technol, State Key Lab Pulp & Paper Engn, Sch Light Ind & Engn, Guangzhou 510640, Peoples R China
推荐引用方式 GB/T 7714	Li, Danni,Zhang, Jun,Liu, Ying,et al. Boron doped magnetic catalysts for selective transfer hydrogenation of furfural into furfuryl alcohol[J]. CHEMICAL ENGINEERING SCIENCE,2021,229:12.
APA	Li, Danni,Zhang, Jun,Liu, Ying,Yuan, Haoran,&Chen, Yong.(2021).Boron doped magnetic catalysts for selective transfer hydrogenation of furfural into furfuryl alcohol.CHEMICAL ENGINEERING SCIENCE,229,12.
MLA	Li, Danni,et al."Boron doped magnetic catalysts for selective transfer hydrogenation of furfural into furfuryl alcohol".CHEMICAL ENGINEERING SCIENCE 229(2021):12.