Earth-abundant Metal-catalyzed Reductive Amination: Recent Advances and Prospect for Future Catalysis

doi:10.1002/asia.202100473

	Earth-abundant Metal-catalyzed Reductive Amination: Recent Advances and Prospect for Future Catalysis
	Liu, Jianguo 1,2; Song, Yanpei 2; Ma, Longlong 2
刊名	CHEMISTRY-AN ASIAN JOURNAL
	2021-07-29
页码	22
关键词	Earth-abundant metal reductive amination carbonyl compounds amines
ISSN号	1861-4728
DOI	10.1002/asia.202100473
通讯作者	Liu, Jianguo(liujg@ms.giec.ac.cn) ; Ma, Longlong(mall@ms.giec.ac.cn)
英文摘要	Nitrogen-containing compounds, as an important class of chemicals, have been used widely in pharmaceuticals, materials synthesis. Transition metal-catalyzed reductive amination of an aldehyde or a ketone with ammonia or an amine has been proved to be an efficient and practical method for the preparation of nitrogen-containing compounds in academia and industry for a century. Given the above, several effective methods using transition metals have been developed in recent years. Noble transition metals like Pd, Pt, and Au-based catalysts have been predominately used in reductive amination. Because of their high prices, strict official regulations of residues in pharmaceuticals, and deleterious effects on the biological system, their industrial applications are severely hampered. With the increasing sustainable and environmental problems, the Earth-abundant transition metals including Ti, Fe, Co, Ni, and Zr have also been investigated for the reductive amination reaction and showed great potential to the advancement of sustainable and cost-effective reductive amination processes. This critical review will mainly summarize the work using Earth-abundant metals. The effects of different transition metals used in catalytic reduction amination were discussed and compared, and some suggestions were given. The last section highlights the catalytic activities of bi- and tri-metallic catalysts. Indeed, this latter family is very promising and simultaneously benefits from increased stability, and selectivity, compared to monometallic NPs, due to synergistic substrate activation. Few comprehensive reviews focusing on Earth-abundant transition metals catalyst has been published since 1948, although several authors reported some summaries dealing with one or the other part of this aspect. It is hoped that this critical review will inspire researchers to develop new efficient and selective earth-abundant metal catalysts for highly, environmentally sustainable reductive amination methods, as well as improve the pharmaceutical industry and related chemical synthesis company traditional method with the utilization of the green method widely.
资助项目	National Key R&D Program of China[2018YFB1501500] ; National Natural Science Foundation of China[51976225] ; Dalian National Laboratory Cooperation Foundation[DNL201916]
WOS关键词	CARBONYL-COMPOUNDS ; SECONDARY-AMINES ; NITRO-COMPOUNDS ; COBALT NANOPARTICLES ; SUBSTITUTED AMINES ; GENERAL-SYNTHESIS ; AQUEOUS AMMONIA ; HYDROGEN DONOR ; LEVULINIC ACID ; IRON COMPLEX
WOS研究方向	Chemistry
语种	英语
出版者	WILEY-V C H VERLAG GMBH
WOS记录号	WOS:000678809200001
资助机构	National Key R&D Program of China ; National Natural Science Foundation of China ; Dalian National Laboratory Cooperation Foundation
内容类型	期刊论文
源URL	[http://ir.giec.ac.cn/handle/344007/33554]
专题	中国科学院广州能源研究所
通讯作者	Liu, Jianguo; Ma, Longlong
作者单位	1.Chinese Acad Sci, Dalian Natl Lab Clean Energy, Dalian 116023, Peoples R China 2.Chinese Acad Sci, Key Lab Renewable Energy, Guangdong Key Lab New & Renewable Energy Res & De, Guangzhou Inst Energy Convers, Guangzhou 510640, Peoples R China
推荐引用方式 GB/T 7714	Liu, Jianguo,Song, Yanpei,Ma, Longlong. Earth-abundant Metal-catalyzed Reductive Amination: Recent Advances and Prospect for Future Catalysis[J]. CHEMISTRY-AN ASIAN JOURNAL,2021:22.
APA	Liu, Jianguo,Song, Yanpei,&Ma, Longlong.(2021).Earth-abundant Metal-catalyzed Reductive Amination: Recent Advances and Prospect for Future Catalysis.CHEMISTRY-AN ASIAN JOURNAL,22.
MLA	Liu, Jianguo,et al."Earth-abundant Metal-catalyzed Reductive Amination: Recent Advances and Prospect for Future Catalysis".CHEMISTRY-AN ASIAN JOURNAL (2021):22.